Abstract:We report on the reversible, electrochemical (de)fluorination of the defect fluoride pyrochlore CsMnFeF6 at room temperature using a liquid electrolyte. CsMnFeF6 was synthesized via three different methods (hydrothermal, ceramic, and mechanochemical), each of which yield products of varying particle size and phase purity. Using galvanostatic cycling, we found that after three oxidative/ reductive cycles, approximately one fluoride ion can be reversibly inserted and removed from mechanochemically synthesized Cs… Show more
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