Röntgenographische Untersuchungen im System (Zn, Cd)–Sb. II

Halla, F.; Nowotny, H.; Tompa, H.

doi:10.1002/zaac.19332140209

Cited by 13 publications

(6 citation statements)

References 3 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The study of the phase diagram of the Sb-Zn system has been undertaken by many authors [5][6][7][8][9][10][11][12][13][14][15][16][17][18]. Their results are often very unmatched.…”

Section: Bibliographical Analysismentioning

confidence: 99%

Crystallographic study of the intermediate compounds SbZn, Sb3Zn4 and Sb2Zn3

Adjadj

Belbacha

Bouharkat

et al. 2006

Journal of Alloys and Compounds

View full text Add to dashboard Cite

“…The study of the phase diagram of the Sb-Zn system has been undertaken by many authors [5][6][7][8][9][10][11][12][13][14][15][16][17][18]. Their results are often very unmatched.…”

Section: Bibliographical Analysismentioning

confidence: 99%

Crystallographic study of the intermediate compounds SbZn, Sb3Zn4 and Sb2Zn3

Adjadj

Belbacha

Bouharkat

et al. 2006

Journal of Alloys and Compounds

View full text Add to dashboard Cite

“…(c) 3×1×3 cell shows the Zn 2 Sb 2-ring network. Each ring has six nearest neighbours, connected by bonds ix [1][2][3][4][5][6] . (d) The angles between Sb-Zn-Sb are similar to that of the standard tetrahedron, 109.5°.…”

Section: Crystallographic Structure and Covalent Bondsmentioning

confidence: 99%

“…(d) The angles between Sb-Zn-Sb are similar to that of the standard tetrahedron, 109.5°. The bonds i-vi are covalent bonds for building up the tetrahedron, while vii and viii are the bonds to form Zn 2 Sb 2 -ring; bonds ix [1][2][3][4][5][6] in (c) are the dimers, that connect the Zn 2 Sb 2 -rings.…”

Section: Crystallographic Structure and Covalent Bondsmentioning

confidence: 99%

“…Quantitative measurements of the Seebeck voltage of ZnSb have been carried out by Becquerel in 1866 [3], and thermoelectric generators using Zn-Sb alloy were fabricated for practical purposes since 1870 [4]. From the early twentieth century, many attempted to solve the crystal structure, but were barely successful [5][6][7], until Almin, finally, in 1948 determined the crystal structure of ZnSb together with CdSb [8]. A large interest in ZnSb followed and was benefitted by the progress on semiconductors since the 1950s.…”

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Review of Research on the Thermoelectric Material ZnSb

Song¹,

Finstad²

2016

Thermoelectrics for Power Generation - A Look at Trends in the Technology

View full text Add to dashboard Cite

The thermoelectric material ZnSb has been studied intensively in recent years and has shown promising features. The other zinc-antimonide compound, Zn 4 Sb 3 has remarkable low thermal conductivity, but it is accompanied with phase transitions at moderate temperature and has inherent stability problems. Compared to that, ZnSb is relatively phase stable and has a relative high charge carrier mobility and Seebeck coefficient, thus yielding a decent power factor. Meanwhile, its thermal conductivity can be reduced by means of nanostructuring, thus giving a good figure of merit at moderate temperatures, 400-600K. Many researchers have dedicated their efforts to study and improve ZnSb properties, and the figure of merit has been reported to be above one. Still, ZnSb as a thermoelectric material has features and behaviours that are not well-understood. The behaviour and properties of its intrinsic defects are not understood, but have interested researchers in recent years. This chapter intends to offer a comprehensive review on ZnSb to the readers. By combining own experiences from research on thermoelectric materials, the authors address the prospect for improving the thermoelectric properties of ZnSb and the concerns of transferring lab results to manufacturing.

show abstract

“…Published work, thereafter [7][8][9][10][11][12][13][14][15][16], was directed towards the determination of the crystallization fields of the compounds SbZn, Sb 3 Zn 4 and Sb 2 Zn 3 , the existence of polymorphic transformations and the various reactions generated by the presence of these compounds. Fig.…”

Section: Bibliographical Analysismentioning

confidence: 99%