1979
DOI: 10.1021/ja00511a058
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Roles of multiplicity and electronic excitation on intramolecular reactions of alkylcarbenes in condensed phase

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1979
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Cited by 63 publications
(20 citation statements)
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“…Photolysis of ethylmethyldiazirine gives a more complex mixture of products than observed upon pyrolysis of the same precursor. Many more examples of this type were subsequently reported by Shechter and Jones. , …”
Section: Discussionmentioning
confidence: 85%
“…Photolysis of ethylmethyldiazirine gives a more complex mixture of products than observed upon pyrolysis of the same precursor. Many more examples of this type were subsequently reported by Shechter and Jones. , …”
Section: Discussionmentioning
confidence: 85%
“…The long-recognized problem of detangling the chemistry of carbenes from the reactions of their precursors remains incredibly relevant today. ,, The field of chemical biology will benefit from future studies to develop photoaffinity tags with desirable physiochemical properties that can label biological targets via a “real” carbene insertion mechanism.…”
mentioning
confidence: 99%
“…1 While the involvement of excited states of diazirines and diazo compounds can complicate the situation in the photolytic decompositions, it is generally agreed that singlet carbenes, as the first-formed intermediates in thermal processes, can yield insertion and rearrangement products. 2 The complexities of the formation and reactions of tert-butylmethylene have been summarized in a paper by Glick and co-workers.…”
Section: Introductionmentioning
confidence: 99%