“…In the framework of the electrografting of carbon surfaces, examples of the use of redox catalysts are rather scarce. Until we know, there are no examples of reduction, however, such grafting possibility has been explored in the case of amines,, [45–47] alkynyl lithium compounds [48,49] and carboxylates [50,51] . The direct oxidation of these functional groups follows the potential order E amine >E alkynyl‐lithium >E carboxylate , and these potentials are generally found between 0.8 and 1.6 V/SCE.…”