“…S27 (ESI †). The minimal or no hysteresis of the fabricated devices is instigated from the alkoxy chains present in the molecule 12a-d, which can afford humid resistivity and will passivate trap states, [46][47][48][49] causing issues of hysteresis, leakage and high threshold voltages. 24,50,51 For the field-effect transistors, the film morphology and crystalline properties have been widely evidenced to be the main factors determining the mobility of the planarity and extended pi-conjugation, which results in efficient intermolecular interactions to give improved mobility.…”