Molten KF-K 2 NbF 7 -Nb 2 O 5 system has been determined from the point of phase equilibrium, density, viscosity and surface tension. In spite of narrow investigated concentration region, system has been studied only up to 20 mol % of the Nb 2 O 5 ; in the system oxofluoroniobate compounds are formed. These have influence on the physicochemical properties.