“…Therefore, CPDMA exhibits better hydrophobicity, thermal stability, and adhesion properties, all of which are essential for the external encapsulation of PSCs. [ 33,34 ]…”
Polymers play a crucial role in promoting the progress of high‐performance inverted perovskite solar cells (PSCs). However, few polymers have simultaneously achieved defect passivation and device encapsulation in PSCs. Herein, a telechelic silicone polymer (poly(dimethylsiloxane‐co‐methylsiloxane acrylate) [PDMA]) is introduced, which possesses crosslinking capability to enable structure regulation through a condensation reaction. By leveraging the advantages of the polymers before and after crosslinking, a synergistic strategy of defect healing and device encapsulation for PSCs is developed via the application of the targeted polymer. PDMA as additives anchors tightly at the grain boundaries (GBs) and bridges the perovskite grains, achieving defect passivation and GBs crosslinking, increasing the efficiency of inverted PSCs from 22.32% to 24.41%. Crosslinked PDMA (CPDMA) is used as an encapsulant to encapsulate the entire device, enabling non‐destructive encapsulation at room temperature and inhibiting perovskite degradation under photothermal aging. Remarkably, the PDMA‐modified device with CPDMA encapsulation maintains 98% of its initial efficiency after 1200 h under continuous illumination at 55 ± 5 °C and retains 95% of its original efficiency after 1000 h of damp heat testing, meeting one of the IEC61215:2016 standards.
“…Therefore, CPDMA exhibits better hydrophobicity, thermal stability, and adhesion properties, all of which are essential for the external encapsulation of PSCs. [ 33,34 ]…”
Polymers play a crucial role in promoting the progress of high‐performance inverted perovskite solar cells (PSCs). However, few polymers have simultaneously achieved defect passivation and device encapsulation in PSCs. Herein, a telechelic silicone polymer (poly(dimethylsiloxane‐co‐methylsiloxane acrylate) [PDMA]) is introduced, which possesses crosslinking capability to enable structure regulation through a condensation reaction. By leveraging the advantages of the polymers before and after crosslinking, a synergistic strategy of defect healing and device encapsulation for PSCs is developed via the application of the targeted polymer. PDMA as additives anchors tightly at the grain boundaries (GBs) and bridges the perovskite grains, achieving defect passivation and GBs crosslinking, increasing the efficiency of inverted PSCs from 22.32% to 24.41%. Crosslinked PDMA (CPDMA) is used as an encapsulant to encapsulate the entire device, enabling non‐destructive encapsulation at room temperature and inhibiting perovskite degradation under photothermal aging. Remarkably, the PDMA‐modified device with CPDMA encapsulation maintains 98% of its initial efficiency after 1200 h under continuous illumination at 55 ± 5 °C and retains 95% of its original efficiency after 1000 h of damp heat testing, meeting one of the IEC61215:2016 standards.
“…As a kind of natural polyphenol, curcumin contains various active groups, including methylene, phenolic hydroxyl, and β-diketone. 44,45 Therefore, curcumin is facile to be decorated and further functionalized into some unique supramolecular self-assembly structures through reversible hydrogen binding interactions, metal–ligand interactions, and Schiff base bonds. The SPUU elastomers containing various hydrogen bonding sites exhibit promising potential to blend with curcumin through hydrogen bonds.…”
Section: Resultsmentioning
confidence: 99%
“…14,34,35 Integrating these high-performance supramolecular polymers with diverse functions, such as conductivity, stimuli-responsiveness, damping ability, and antibacterial activity, is regarded as a hot spot in the construction of modern society. 26,36–45 However, on some occasions, some special functional components were introduced into the polymer matrix, which leaded to unwanted degeneration in the mechanical performances of polymeric materials. 46–50 For example, the introduction of excess rigid nanofillers such as graphene or carbon nanotubes will stiffen the polymer matrix, while it also will decrease the toughness of the polymers.…”
Developing high-performance functional elastomers that integrate robust mechanical properties with high healing efficiency remains a forbidden challenge due to the conflicts among mechanical strength, toughness, and healing ability. Herein, supramolecular...
“…Inspired by this, researchers have endowed glass, leather, textiles, wood, and buildings with the ability to resist contamination caused by water, bacteria, and dirt. 2,3 However, the hydrophobic component of coating may be destroyed in practical applications because organic grease contaminants tend to adhere to the coating surface, which are not easily eroded and removed by water, resulting in a gradual reduction of hydrophobicity and eventual loss of superhydrophobic selfcleaning property. 4,5 Interestingly, the photocatalytic selfcleaning surface can catalyze the chemical decomposition of organic pollutants into small molecules such as carbon dioxide and water.…”
Section: Introductionmentioning
confidence: 99%
“…As is well-known, the surface of a lotus leaf has a physical self-cleaning performance because of its superhydrophobic property that enables the removal of surface dust. Inspired by this, researchers have endowed glass, leather, textiles, wood, and buildings with the ability to resist contamination caused by water, bacteria, and dirt. , However, the hydrophobic component of coating may be destroyed in practical applications because organic grease contaminants tend to adhere to the coating surface, which are not easily eroded and removed by water, resulting in a gradual reduction of hydrophobicity and eventual loss of superhydrophobic self-cleaning property. , Interestingly, the photocatalytic self-cleaning surface can catalyze the chemical decomposition of organic pollutants into small molecules such as carbon dioxide and water. Therefore, superhydrophobic coatings with photocatalytic activity can not only reject liquids but also photocatalytically degrade organic pollutants.…”
The self-cleaning coating has both superhydrophobic physical and photocatalytic chemical self-cleaning properties, which has attracted the wide attention of researchers in recent years. First, the flower-like hollow SiO 2 @TiO 2 spheres with oxygen vacancies (rFHSTs) were prepared by the liquid-phase reduction method, in which several different functional components were integrated. Meanwhile, the influence mechanisms of the physical structure and chemical composition on the photocatalytic properties are discussed in detail. The results proved that rFHSTs exhibited the enhanced photoresponse range and photocatalytic degradation performance in visible light because of the synergistic effect of the microstructure (internal cavity, 3D flower-like nanosheet), SiO 2 /TiO 2 heterojunction structure, and oxygen vacancies. After that, superhydrophobic modified rFHSTs were used as fillers to fabricate PVA/PFDTS-rFHSTs composite coatings with both physical and chemical selfcleaning properties. The self-cleaning performances and principles of the composite coating were examined and explored. The results showed that the low surface energy of the hydrophobic chain segment, the inherent particle effect, and the photocatalytic activity of rFHSTs were responsible for the superhydrophobic and photocatalytic effects, finally endowing the composite coating with selfcleaning performance. In short, this study is profound for the development and application of self-cleaning coatings with both physical and chemical performances.
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