2023
DOI: 10.24820/ark.5550190.p012.098
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Ring-closing enyne metathesis of allylic and propargylic cyanamides

Jiaqi Fang,
Sébastien Van Laethem,
Nicolas Blanchard
et al.

Abstract: A straightforward entry to 5-membered cyclic cyanamides from readily available allylic and propargylic cyanamides is reported. These starting materials are easily obtained by a multicomponent A 3 coupling followed by a von Braun reaction and they were shown to be readily cyclized by a ring-closing enyne metathesis, upon simple reaction with Grubbs II catalyst, to the corresponding highly functionalized cyclic cyanamides.

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