We show that the liquid-to-crystal quantum phase transition in the Rokhsar-Kivelson dimer model on the two-dimensional triangular lattice occurs as a condensation of vortex-like excitations called "visons". This conclusion is drawn from the numerical studies of the vison spectrum in the liquid phase by using the Green's function Monte Carlo method. We find that visons remain the lowest excitation throughout the liquid phase and that their gap decreases continuously to zero at the phase transition. The nature of the crystal phase and the second order of the phase transition are in agreement with the earlier prediction of Moessner and Sondhi [Phys. Rev. B 63, 224401 (2001)].The resonating valence bond (RVB) liquid is one of the most intriguing concepts of today's condensed-matter physics. Conjectured over thirty years ago for frustrated spin systems, [1] it still lacks an adequate quantitative description, and even its emergence in real physical materials or in realistic spin models is not rigorously established. In the early days of the RVB paradigm, it has been realized that such a state should be characterized by a Z 2 topological order whose most prominent consequence is the vortex-like excitation [2] later dubbed "vison".[3] This type of excitations should be important for the thermodynamics of RVB spin liquids and serve as a "smoking gun" of the RVB phase. Numerically, low-lying singlet excitations have been found in the Kagome spin-1/2 Heisenberg antiferromagnet, [4] the most promising candidate for the RVB spin-liquid state, and these singlets have been interpreted as RVB states in the subspace of nearest-neighbor singlet dimers.[5] Experimentally, the spin-1/2 Kagome system with a possible spin-liquid phase has been realized recently in the ZnCu 3 (OH) 6 Cl 2 compound.[6] A variational study of this system with Gutzwiller-projected wave functions also predicts lowlying excitations of the gauge field [U(1) instead of Z 2 ]. [7] Thus the properties of the low-lying collective singlet excitations is one of the central questions in the study of RVB states.To model the vison branch of excitations in the RVB state, it has been proposed to use dimer models instead of spin ones. [8] In dimer models, the spin degrees of freedom are explicitly frozen, and only the vison excitations survive. Regardless of its relation to microscopic spin models, the quantum dimer model (QDM) of Rokhsar and Kivelson (RK) has attracted a lot of attention as a promising way to investigate RVB physics, especially on the triangular lattice. The QDM is defined by:where the sum runs over all plaquettes (rhombi) including the three possible orientations. The kinetic term controlled by the amplitude t flips the two dimers on every flippable plaquette, i.e., on every plaquette with two parallel dimers, while the potential term controlled by the interaction V describes a repulsion (V > 0) or an attraction (V < 0) between nearest-neighbor dimers. For dimer models, the situation is much more definite than for spin systems: The RVB phase is firml...