Abstract:An efficient synthetic method of tetracyclic 3,4-fused indoles and dihydroindoles via rhodium-catalyzed (3+2) cycloaddition of N-tosyl-4-(2-phenoxyphenyl)-1,2,3-triazole was described. The aromatized xanthene derivatives can be achieved in a one-pot synthesis starting from 1-ethynyl-2-phenoxybenzene. The xanthene-based fused heterocycles were considered as the valuable fluorophore.
The reaction of 1-alkyl-1H-1,2,3-triazoles with rhodium(ii) azavinyl carbenes, generated from 1-sulfonyl-1H-1,2,3-triazoles, was utilized to prepare 3-sulfonamido-1H-pyrroles and 1,2,3-triazol-3-ium ylides in good yields.
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