Rhodium(i) Aryldiisocyanide Polymers

Engineering Metal Organic Frameworks for Heterogeneous Catalysis

“…In successive years, the same group has reported on the preparation and catalytic activity of hybrid materials related with the above Rh-containing CP. In particular, they described the preparation of CPs containing 4,4′-diisocyanobiphenyl (4,4′-dicbp) as the organic ligand and Pd, Pt (both metals in 0 or II oxidation state), , and Rh(I) as the metallic components. These materials were also found to be active for the heterogeneous hydrogenation of alkenes and alkynes.…”

Tetragonal co-ordination polymers of rhodium(I) with stereochemically rigid aryl di-isocyanide linkages

“…The { [Rh(L),]CI}, polymers show catalytic activity in the hydrogenation and isomerization of hex-1 -ene in methanolic solutions. 18 The percentage of rhodium surface sites in the ([Rh{ (C,H,NC-p),},]CI}, polymer decreases as n increases. We have reported the preparation and characterization of similar co-ordination polymers, [( RhCI(CO)[C,-H,(NC)z-1,4],)n].…”

A catalytically active porous coordination polymer based on a dinuclear rhodium paddle-wheel unit

“…in the well studied HKUST-1 (HKUST -Hong Kong University of Science and Technology). 11 In previous years a number of coordination polymers based on diisocyano ligands and ruthenium, 12,13 palladium, 14,15 platinum, 14,15 iridium 16 and rhodium 16,17 were prepared and their catalytic activity was investigated. In 2006, Navarro et al reported on the compound [Pd(2-pymo) 2 ] n (pymo ¼ 2-pyrimidinolate) and thus the rst MOF based on palladium.…”