Rhodium‐Catalyzed Carbonylations

CO and H2 gas-free efficient reductive carbonylation of aryl iodides. Use of smart recyclable metal-based catalysts

“…Moreover, some carbon monoxide surrogates are easily transportable and available from waste biomass (e.g., paraformaldehyde, methanol, oxalates, formates etc.) [8,24,25]. Recently, a palladium-catalyzed CO-free carbonylative procedure for the synthesis of aromatic aldehydes from aryl iodides was described [1].…”