Abstract:The effect of the network-to-molecular structural transformation with increasing phosphorus content in P xSe 100-x (30 {less than or equal to} x {less than or equal to} 67) supercooled liquids on their shear-mechanical response is investigated using oscillatory shear rheometry. While network liquids with 30 {less than or equal to} x {less than or equal to} 40 are characterized by shear relaxation via a network bond scission/renewal process, a Maxwell scaling of the storage (G') and loss (G') shear moduli and a… Show more
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