Rheological behavior of N,N‐dimethyl acrylamide–acrylamido methylpropane sulphonate copolymer

Abstract

ABSTRACT:Copolymer of N,N-dimethylacrylamide (NNDAM) and sodium 2-acrylamido-2-methylpropanesulfonate (NaAMPS) have been prepared by free-radical copolymerization and characterized with the help of molecular weight, molecular weight distribution, intrinsic viscosity, and monomer ratio in the copolymer. The solution behavior of a copolymer containing 26.62 wt % NaAMPS is studied in different solvents, namely, water (W), dimethyl sulfoxide (DMSO), ethylene glycol (EG), and ethanol (EtOH). The reduced viscosity of the copolymer is highly dependent on the ionic strength of the copolymer solution. The reduced viscosity decreases as a function of solvent selection in the order W Ͼ DMSO Ͼ EtOH Ͼ EG. The shapes of the sp / C vs. C plots indicate the polyelectrolyte behavior of the copolymer, except for the case of EG solutions, where nonpolyelectrolyte behavior is observed. However, at a certain degree of ionization attained by adding W as cosolvent, the copolymer begins to demonstrate polyelectrolyte behavior. For this copolymer, there exists a minimum concentration of brine (NaCl, CaCl 2 , etc.) above which solution viscosity is not further reduced. The copolymer solution behaves as a power law fluid, and exhibits time-dependent thixotropic behavior. The copolymer cannot regain its solution viscosity when allowed to shear at a constant rate for long period of time. The reduced viscosities of copolymer solutions increase with increasing temperature in W and DMSO, yet decreases with increasing temperature in EG.