Rh(iii)-catalyzed selective C2 C–H acyloxylation of indoles

Abstract

The first highly selective C2 C–H acyloxylation of indole under rhodium catalysis and an N-quinolinyl auxiliary is reported.

Electrochemically enabled cobalt catalyzed enantioselective C–H acyloxylation of aryl phosphamide with carboxylic acid

“…Over the past decades, this field has received continuous attention, resulting in the development of various methodologies. These methods employ versatile catalysts such as Pd, 1 Rh, 2 Ru, 3 Co, 4 and Cu 5 to promote C–H acyloxylation under oxidative conditions, as illustrated in Scheme 1a. Strategies for enantioselective C–H acyloxylation are less advanced compared to other areas.…”