Free-standing TiNT array film was successfully synthesized by a one-step anodization method. The characteristic techniques including scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray diffraction (XRD) were adopted to characterize the morphology and chemical composition of the TiNT array film. Subsequently, gas sensor based on the TiNT array film was fabricated and its sensing performance toward H 2 S was investigated. The results showed that the optimum operating temperature to detect H 2 S gas was 300℃, the detection range to H 2 S gas was 1-50 ppm with the response value of 4.5-26.2, and a *Manuscript Click here to view linked References good linearity of sensing characteristics could be observed. Meanwhile, the response and recovery time of the sensor to 50 ppm H 2 S gas were as low as 22 s and 6 s, respectively. In addition, mechanisms of the development of the free-standing TiNT array film and the sensor towards H 2 S were discussed. In conclusion, its outstanding sensing properties and readily fabrication of the TiNT array film sensor presented the potential industrial applications.