“…By rational design and appropriate selection of constituents and concentration, DESs could be designed to be low-cost, biodegradable, and task-specific. − Although there are some disputes on the nature, greenness, and high viscosity of DESs, − DESs have attracted much attention as a result of the low melting point, easy synthesis, wide liquid range, and high tunability. , DESs are regarded as analogous ionic liquids (ILs); both DESs and ILs show a liquid state near room temperature, own lower volatility than volatile organic compounds (VOCs), and have high designability. − DESs are easier to be prepared, and the atom efficiency of DESs is higher than that of ILs; in this sense, DESs are deemed as IL alternatives . Some DESs are reported to be unstable , and toxic; − instead, it could be overcome by applying the high tunability of DESs. Therefore, DESs have been applied in many fields, ,− including acting as green solvents for lithium-ion battery (LIB) dissolution and recovery. − …”