Review on the preparation of carbon membranes derived from phenolic resins for gas separation: From petrochemical precursors to bioresources

Torres, Daniel; Pérez-Rodríguez, S.; Laetitia, Cesari; Castel, Christophe; Favre, Éric; Fierro, Vanessa; Celzard, Alain

doi:10.1016/j.carbon.2021.06.087

Cited by 42 publications

(17 citation statements)

References 177 publications

(302 reference statements)

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“…A branch of carbon science and technology involves the preparation of carbon materials from phenolic resins (Effendi et al, 2008;Celzard and Fierro, 2020;Szczesniak et al, 2020;Torres et al, 2021). Phenolic resins are synthetic polymeric compounds that are obtained from the condensation reaction of phenolic molecules with or without a crosslinking agent (Sarika et al, 2020).…”

Section: Introductionmentioning

confidence: 99%

Progress in the Use of Biosourced Phenolic Molecules for Electrode Manufacturing

et al. 2022

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In the era of renewable technologies and clean processes, carbon science must adapt to this new model of a green society. Carbon materials are often obtained from petroleum precursors through polluting processes that do not meet the requirements of sustainable and green chemistry. Biomass is considered the only renewable source for the production of carbon materials, as the carbon in biomass comes from the consumption of carbon dioxide from the atmosphere, resulting in zero net carbon dioxide emissions. In addition to being a green source of carbon materials, biomass has many advantages such as being a readily available, large and cheap feedstock, as well as the ability to create unique carbon-derived structures with well-developed porosity and heteroatom doping. All these positive aspects position biomass-derived carbon materials as attractive alternatives in multiple applications, from energy storage to electrocatalysis, via adsorption and biosensors, among others. This review focuses on the application of phenolic resins to the production of electrodes for energy storage and the slow but inexorable movement from petroleum-derived phenolic compounds to biosourced molecules (i.e., lignins, tannins, etc.) as precursors for these carbon materials. Important perspectives and challenges for the design of these biosourced electrodes are discussed.

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Section: Introductionmentioning

confidence: 99%

Progress in the Use of Biosourced Phenolic Molecules for Electrode Manufacturing

et al. 2022

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“…It is widely used in construction, transportation, electronics, and aerospace because of its low cost, simple molding process, excellent mechanical properties, and heat resistance. [1][2][3][4] However, PF exhibits high brittleness and low-impact strength due to the closely packed rigid aromatic rings attached to the methylene groups during the curing process. Moreover, PF has relatively low-thermal stability because of the presence of phenolic hydroxyl and methylene groups.…”

Section: Introductionmentioning

confidence: 99%

Enhanced thermal stability and impact strength of phenolic formaldehyde resin using acid‐treated basalt scales

Tang

Jin

et al. 2022

J of Applied Polymer Sci

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In this study, phenolic formaldehyde (PF) resin-based composites were prepared using basalt scale (BS) as a reinforcing agent via a melting-blending method. The BS surface was treated with hydrochloric acid, and the surface properties were characterized using thermal field-emission scanning electron microscopy, Fourier-transform infrared, X-ray photoelectron spectrometry, and energy-dispersive X-ray spectroscopy. Moreover, the influence of acidtreated BS (H-BS) content on the thermal properties, flexural properties, impact strength, and morphology of PF/H-BS composites was investigated. The thermal stability and glass transition temperature of the composites increased significantly with the increasing H-BS content. The impact strength tests indicated that the impact strength of the composite with 15 wt% H-BS was 0.66 kJ/m 2 , which is 153% higher than that of pristine PF. The scanning electron microscopy results indicated that the PF/H-BS composites exhibit rough morphology with numerous microcracks.

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“…Phenol plays a significant role in the petroleum, plastics, pharmaceutical and leather industries, 1 for it is the feed stock of phenolic resin, caprolactam, bisphenol A, and other chemical products or intermediates. 2,3 The global demand for phenol has rocketed in recent years, and the amount of phenol in wastewater has increased accordingly.…”

Section: Introductionmentioning

confidence: 99%

Mechanism in chlorine‐enhanced Pd catalyst for H₂O₂in situ synthesis in electro‐Fenton system

Shu

Zhang

et al. 2022

AIChE Journal

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Palladium-based catalysts have been widely employed in the electro-Fenton process for in situ generation of H 2 O 2 . However, the process is still far from being practical on a large scale. In this work, a series of Cl x FePd/γ-Al 2 O 3 /Al catalysts were prepared by a three-step-impregnation method. They exhibited excellent activity in H 2 O 2 in situ synthesis and high efficiency in phenol degradation. The characterization results showed that Cl could assist in increasing the content of Pd 0 and reducing the isoelectric point of catalysts, which led to the drastic promotion in the synthesis of H 2 O 2 .Theoretical calculations further demonstrated that Cl doping could facilitate the main reaction in H 2 O 2 synthesis, as well as inhibit side reactions such as dissociation of the O O bond. Furthermore, kinetic models were proposed and fitted. A plausible reaction mechanism as well as degradation pathways were elaborated based on electron spin resonance and gas chromatography-mass spectrometry results. These findings illustrate the value of palladium-based Cl x FePd/γ-Al 2 O 3 /Al catalysts for their application in the electro-Fenton process.

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Review on the preparation of carbon membranes derived from phenolic resins for gas separation: From petrochemical precursors to bioresources

Cited by 42 publications

References 177 publications

Progress in the Use of Biosourced Phenolic Molecules for Electrode Manufacturing

Progress in the Use of Biosourced Phenolic Molecules for Electrode Manufacturing

Enhanced thermal stability and impact strength of phenolic formaldehyde resin using acid‐treated basalt scales

Mechanism in chlorine‐enhanced Pd catalyst for H₂O₂in situ synthesis in electro‐Fenton system

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Review on the preparation of carbon membranes derived from phenolic resins for gas separation: From petrochemical precursors to bioresources

Cited by 42 publications

References 177 publications

Progress in the Use of Biosourced Phenolic Molecules for Electrode Manufacturing

Progress in the Use of Biosourced Phenolic Molecules for Electrode Manufacturing

Enhanced thermal stability and impact strength of phenolic formaldehyde resin using acid‐treated basalt scales

Mechanism in chlorine‐enhanced Pd catalyst for H2O2in situ synthesis in electro‐Fenton system

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Mechanism in chlorine‐enhanced Pd catalyst for H₂O₂in situ synthesis in electro‐Fenton system