Abstract:Dewetting is the main damage mode of composite solid propellants, and the research on the initiation mechanism and evolution process of dewetting damage is an important way to predict the mechanical properties and evaluate the life of propellants. In this paper, the experimental research and analytical methods of dewettingare reviewed at domestic and foreign from three dimensions: macro, meso and micro. On this basis, the reference solutions to the existing research problems are proposed, and the key research … Show more
“…Representative volume element (RVE)-based [ 17 , 18 , 19 ] mesoscale and microscale models play important roles in studying the multi-scale mechanical properties of PFPCs. In particular, the RVE combined with the cohesive zone model (CZM) [ 20 , 21 , 22 ] has been widely used to simulate particle debonding in PFPCs, which is also named dewetting in some of the literature [ 23 , 24 , 25 ].…”
In this study, the aging performance of particle-filled polymer composites (PFPCs) under thermo-oxidative conditions was investigated on multiple scales. High-temperature-accelerated tests were conducted to analyze the effects of aging time and temperature. A representative volume element (RVE) model was established for the PFPCs using a random particle-filling algorithm. A predictive model for the crosslink density was conducted based on the closed-loop chain reaction of polymer oxidation. According to the theory of polymer physics, the relation between the crosslink density and matrix modulus was determined. The particle/matrix interface in the RVE model was represented by the cohesive zone model (CZM). The parameters of the CZM were determined by the inversion techniques. Then, a comprehensive multiscale RVE model was constructed, which was applied to predict the modulus and dewetting strain of the aged PFPCs. The predicted results show good agreement with the test results, which verifies the reliability of our model.
“…Representative volume element (RVE)-based [ 17 , 18 , 19 ] mesoscale and microscale models play important roles in studying the multi-scale mechanical properties of PFPCs. In particular, the RVE combined with the cohesive zone model (CZM) [ 20 , 21 , 22 ] has been widely used to simulate particle debonding in PFPCs, which is also named dewetting in some of the literature [ 23 , 24 , 25 ].…”
In this study, the aging performance of particle-filled polymer composites (PFPCs) under thermo-oxidative conditions was investigated on multiple scales. High-temperature-accelerated tests were conducted to analyze the effects of aging time and temperature. A representative volume element (RVE) model was established for the PFPCs using a random particle-filling algorithm. A predictive model for the crosslink density was conducted based on the closed-loop chain reaction of polymer oxidation. According to the theory of polymer physics, the relation between the crosslink density and matrix modulus was determined. The particle/matrix interface in the RVE model was represented by the cohesive zone model (CZM). The parameters of the CZM were determined by the inversion techniques. Then, a comprehensive multiscale RVE model was constructed, which was applied to predict the modulus and dewetting strain of the aged PFPCs. The predicted results show good agreement with the test results, which verifies the reliability of our model.
Considering the high toxicity of toluene diisocyanate (TDI) and the low reactivity of isophorone diisocyanate (IPDI), a low‐toxicity curing agent, dimer acid diisocyanate (DDI), was used to cross‐link HTPB elastomers and propellants. The unique long‐chain structure of DDI not only ensures the elastic modulus and tensile strength of the elastomer, but also improves the flexibility to some extent. The long flexible chains promote the segment movement, which is very important for the formation of hydrogen bonds between segments. The chemical cross‐linking network and hydrogen bonding association play a significant role in the mechanical properties of the HTPB/DDI system. The relationship between the mole ratio of ‐NCO to ‐OH (R‐value) and the mechanical properties of HTPB/DDI elastomers were also investigated. In the range of R‐value from 0.85 to 1.2, the elastic modulus and tensile strength first increase and then decrease, and the elongation at break first decreases and then increases. Under the same curing conditions, the elastic modulus and tensile strength of the HTPB/DDI propellant are similar to the HTPB/TDI propellant. For the HTPB/AP/Al propellants and HTPB/AP/RDX/Al propellants, the HTPB/DDI system has lower burning rates in the range of 5–19 MPa than the HTPB/TDI system and HTPB/IPDI system. The application of DDI can reduce the burning rates of the propellant without adding any burning rate modifiers. It is considered that DDI can replace TDI and IPDI as a new curing agent with low toxicity and moderate reactivity for HTPB systems.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.