Review on the Chemistry of [M(NH<sub>3</sub>)<sub>n</sub>](XO<sub>4</sub>)<sub>m</sub> (M=Transition Metal, X=Mn, Tc or Re, n=1-6, m=1-3) Ammine Complexes
Abstract:The preparation of transition metal salt ammine complexes having oxidizing anions is a great challenge due to the reaction between the ammonia and oxidizing anions during the synthesis of these materials. However, they have an important role in the development of new oxidants in organic chemistry and especially as precursors in the preparation of mixed metal oxides and alloys in controlled temperature thermal decomposition reactions. Therefore, the synthetic procedures to prepare the complexes of transition me… Show more
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