“…[25][26][27] The chemically synthesized multi-component capacitance electrode widens into vivid nanostructures for specic capacity, energy, power density, rate capability and cycling stability. [28][29][30][31] With the above reported results, an attempt is made to obtain an insightful understanding on the role of the graphene structure in ZIF-8-derived surfaces.…”
By exposing more interfaces, utility of heterostructured electrodes in capacitance retention has been further expanded to devices with a large-scale 3D network. IGO@ZIF-8-NC was described as a symmetric supercapacitor device which paves the way forward for sustainable capacitive devices.
“…[25][26][27] The chemically synthesized multi-component capacitance electrode widens into vivid nanostructures for specic capacity, energy, power density, rate capability and cycling stability. [28][29][30][31] With the above reported results, an attempt is made to obtain an insightful understanding on the role of the graphene structure in ZIF-8-derived surfaces.…”
By exposing more interfaces, utility of heterostructured electrodes in capacitance retention has been further expanded to devices with a large-scale 3D network. IGO@ZIF-8-NC was described as a symmetric supercapacitor device which paves the way forward for sustainable capacitive devices.
“…These can perform ion exchange in both surface and bulk materials . Combination of cobalt oxides with other transition-metal oxides increases the specific capacitance of the capacitor. − …”
High-rate aqueous hybrid supercapacitors (AHSCs) have attracted relevant scientific significance owing to their expected energy density, supercapacitor-level power density, and battery-level energy density. In this work, a bimetallic nanostructured material with chromium-incorporated cobalt oxide (CCO, i.e., CoCr 2 O 4 ) was prepared via a hydrothermal method to form a stable cubic obelisk structure. Compared with CCO materials prepared using traditional methods, CCO displayed a nanowire structure (50 nm diameter), suggesting an enhanced specific surface area and a large number of active sites for chemical reactions. The electrode possessed a high specific capacitance (2951 F g −1 ) at a current density of 1 A g −1 , minimum R ct (0.135 Ω), and the highest capacitance retention (98.7%), making it an ideal electrode material for AHSCs. Ex situ analysis based on X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) showed a favorable stability of CCO after 10,000 cycles without any phase changes being detected. GGA and GGA + U methods employed in density functional theory (DFT) also highlighted the enhanced metallic properties of CCO originating from the synergistic effect of semiconducting Cr 2 O 3 and Co 3 O 4 materials.
“…Binary transition metal oxides have been considered to be promising candidates as electrodes for high-performance pseudo-capacitors due to their multiple redox reactions and high electrical conductivity [ 3 , 4 , 5 ]. Because of the various redox reactions and high conductivity, transition bimetallic oxides are regarded as the best candidates for high-performance pseudocapacitor electrode materials [ 6 , 7 ].…”
Dandelion-like CuCo2O4 nanoflowers (CCO NFs) with ultrathin NiMn layered double hydroxide (LDH) shells were fabricated via a two-step hydrothermal method. The prepared CuCo2O4@NiMn LDH core/shell nanoflowers (CCO@NM LDH NFs) possessed a high specific surface area (~181 m2·g−1) with an average pore size of ~256 nm. Herein, the CCO@NM LDH NFs exhibited the typical battery-type electrode material with a specific capacity of 2156.53 F·g−1 at a current density of 1 A·g−1. With the increase in current density, the rate capability retention was 68.3% at a current density of 10 A·g−1. In particular, the 94.6% capacity of CCO@NM LDH NFs remains after 2500 cycles at 5 A·g−1. An asymmetric supercapacitor (ASC) with CCO@NM LDH NFs//activated carbon (AC) demonstrates a remarkable capacitance of 303.11 F·g−1 at 1 A·g−1 with excellent cycling stability. The coupling and synergistic effects of multi-valence transition metals provide a convenient channel for the electrochemical process, which is beneficial to spread widely within the realm of electrochemical energy storage.
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