The deposition of binary M-ZrO 2 (M = Al 2 O 3 , SiO 2 or TiO 2 ) as secondary support on cordierite substrate by dip-coating was investigated and the as-prepared M-ZrO 2 /cordierite was characterized by means of XRD and SEM techniques. After two successive dip-coating processes, the highest washcoat loading of 25.1% was achieved in Al 2 O 3 -ZrO 2 /cordierite, followed by 18.7% in TiO 2 -ZrO 2 /cordierite and then 17.4% in SiO 2 -ZrO 2 /cordierite. The optimal parameters to prepare Al 2 O 3 -ZrO 2 washcoat on cordierite were investigated in detail. After introduction of noble metal active components (Rh and Pd) to the secondary support, the obtained Rh/M-ZrO 2 /cordierite and Pd/M-ZrO 2 /cordierite were further tested as monolithic catalysts for the decomposition of nitrous oxide and the deep oxidation of benzene, respectively.