Review of the solubility of non-metals in liquid lithium

Adams, Paul F.; Hubberstey, Peter; Pulham, R. J.

doi:10.1016/0022-5088(75)90014-4

Cited by 49 publications

(13 citation statements)

References 17 publications

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“…The growth of the one-dimensional (1D) nanostructures can be rationalised in terms of a self-assisted vapour–liquid–solid (VLS) mechanism. Under vacuum, Li 3 N will decompose at a temperature below the ambient pressure decomposition temperature (815 °C; ΔH (298K) = −171.3 +/− 7.7 kJ mol −1 ) 7 , 8 (Eq. 1 ), forming droplets of liquid Li, since the melting point of Li ( T = 180.5 °C) lies well below the applied reaction temperatures.…”

Section: Resultsmentioning

confidence: 99%

“…Given the exceptional Li + fast ionic conducting properties of bulk Li 3 N, we wished to understand how the ionic transport might vary as a consequence of nanostructuring. Variable-temperature wideline 7 Li solid-state nuclear magnetic resonance (NMR) measurements between 133 and K enabled the local structure of the type I and type II nanofibres to be probed and allowed the Li + ion transport properties of the Li 3 N nanofibres to be determined (Fig. 4 Table 3).…”

Section: Synthesis and Characterisation LI 3 N Nanocrystals Grow Folmentioning

confidence: 99%

“…In both cases, a small condenser aperture was used to reduce beam damage (the result of which is evident inSupplementary Fig. 12) and evaporation due to the instability of nanoscale Li 3 N under the beam 7. Li NMR spectroscopy.…”

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Low dimensional nanostructures of fast ion conducting lithium nitride

et al. 2020

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As the only stable binary compound formed between an alkali metal and nitrogen, lithium nitride possesses remarkable properties and is a model material for energy applications involving the transport of lithium ions. Following a materials design principle drawn from broad structural analogies to hexagonal graphene and boron nitride, we demonstrate that such low dimensional structures can also be formed from an s-block element and nitrogen. Both one- and two-dimensional nanostructures of lithium nitride, Li3N, can be grown despite the absence of an equivalent van der Waals gap. Lithium-ion diffusion is enhanced compared to the bulk compound, yielding materials with exceptional ionic mobility. Li3N demonstrates the conceptual assembly of ionic inorganic nanostructures from monolayers without the requirement of a van der Waals gap. Computational studies reveal an electronic structure mediated by the number of Li-N layers, with a transition from a bulk narrow-bandgap semiconductor to a metal at the nanoscale.

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Section: Resultsmentioning

confidence: 99%

Section: Synthesis and Characterisation LI 3 N Nanocrystals Grow Folmentioning

confidence: 99%

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Low dimensional nanostructures of fast ion conducting lithium nitride

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“…sulfur produces a blue plasma). 30,31 We attribute the onset of this plasma formation to an increase in temperature and a variation in the N 2 partial pressure inside the nitrogen-filled reaction vessel caused by the decomposition of Li 3 N, which occurs at ∼800 °C (ΔH = −171.3 kJ mol −1 ) (eqn (1)): 32,33…”

Section: Resultsmentioning

confidence: 99%

Ultra-rapid microwave synthesis of Li_3−x−yM_xN (M = Co, Ni and Cu) nitridometallates

Tapia‐Ruiz

Laveda

Smith

et al. 2015

Inorg. Chem. Front.

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Single phase nitridometallates Li 3−x−y M x N (0.05 ≤ x ≤ 0.27; M = Co, Ni and Cu) with potential use as negative electrodes in lithium (Li + ) ion batteries have been synthesised in <10 minutes via solid state reactions in a single mode cavity microwave reactor without an external susceptor. Reaction times are reduced by up to four orders of magnitude over previous synthetic methods. A combination of powder X-ray and neutron diffraction has provided detailed crystal structures of the vacancy-disordered nitrides. The electrochemical performance of these materials is comparable to that observed in conventionally-heated analogues. † Electronic supplementary information (ESI) available: Refinement procedures, lattice parameters from XRD, thermal displacement parameters, structure plot, refinement profile plots, schematic and photographs of the synthesis set-up. See b ISIS Facility, Rutherford Appleton Laboratory, Harwell Oxford, Didcot OX11 0QX, UK This journal is

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“…The first data on the liquidus line in Li-LiH -LiD systems below 624˚C were published by a group of British scientists headed by Adams and Hubberstey [1,[5][6][7][8][9]. The solubility was determined from the change in the electrical resistance during the dissolution of H 2 or D 2 in lithium and from the precipitation at the time of saturation.…”

Section: Behavior Of Isothermmentioning

confidence: 99%

Thermodynamic Properties of Li-LiH (LiD, LiT) Systems. The Phase Diagram

Yakimovich¹,

Biryukova²

2012

OJPC

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The paper presents a comprehensive critical review and detailed analysis of the literature, published in the field of the phase diagram solution Li-LiH (LiD, LiT). Special attention is paid to the completeness of the source information on the paper's topic resulting in an extended reference list. Particularly, paper reviews rarely used sources including littleknown publications from research centers, proceedings of the international scientific meetings and dissertations. These publications were more thoroughly analyzed in order to make the information available to the scientific society.

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Review of the solubility of non-metals in liquid lithium

Cited by 49 publications

References 17 publications

Low dimensional nanostructures of fast ion conducting lithium nitride

Low dimensional nanostructures of fast ion conducting lithium nitride

Ultra-rapid microwave synthesis of Li_3−x−yM_xN (M = Co, Ni and Cu) nitridometallates

Thermodynamic Properties of Li-LiH (LiD, LiT) Systems. The Phase Diagram

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Review of the solubility of non-metals in liquid lithium

Cited by 49 publications

References 17 publications

Low dimensional nanostructures of fast ion conducting lithium nitride

Low dimensional nanostructures of fast ion conducting lithium nitride

Ultra-rapid microwave synthesis of Li3−x−yMxN (M = Co, Ni and Cu) nitridometallates

Thermodynamic Properties of Li-LiH (LiD, LiT) Systems. The Phase Diagram

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Ultra-rapid microwave synthesis of Li_3−x−yM_xN (M = Co, Ni and Cu) nitridometallates