Abstract:Many U. S. nuclear power plants are approaching 40 years of age and there is a desire to extend their life for up to 100 total years. Safety-related cables were originally qualified for nuclear power plant applications based on IEEE Standards that were published in 1974. The qualifications involved procedures to simulate 40 years of life under ambient power plant aging conditions followed by simulated loss of coolant accident (LOCA). Over the past 35 years or so, substantial efforts were devoted to determining… Show more
“…This result is simply due to the fact that the TED values are constant, but it is still important from a practical viewpoint. Namely, this proportional relationship and its slope are called the chemical dose-rate effect and the thermal line, respectively [16]. Where the DED value begins to become inclined, it represents quasi "equal dose equal damage" behavior [28,29].…”
Section: Simulation Of the Dose To Equivalentmentioning
confidence: 99%
“…Equation (16) shows that a T can be estimated to understand the temperature effect on the chemical reaction and the TED values by taking 1/T -1/T ref as a temperature parameter, even in this situation.…”
Section: Degradation Phenomena In Wide Temperature Rangesmentioning
confidence: 99%
“…Various degradation phenomena have been investigated for polymeric insulating materials exposed to both heat and radiation [14][15][16]. Containment is determined in terms of these two degradation factors, and the average temperature and radiation dose rate are approximately 50 °C and ~10 -3 Gy/h, respectively [14].…”
A new degradation model for safety cables in nuclear power plants that incorporates the critical antioxidant concentration concept is proposed in order to account for the effect of antioxidants and to simulate several synergisms in various thermal and radiation environments. A chemical reaction scheme is used to represent oxidation reactions via the decomposition of peroxide radicals. The effects of antioxidants are included in this scheme in order to demonstrate critical concentration phenomena. In addition, diffusion equations are added to the reaction rate equations to enable reproduction of diffusion-limited oxidation. Such a degradation model with antioxidant effects is discussed for degradation behaviors in polymers used for safety cables under various dose rates and temperature conditions, and its effectiveness is verified.
“…This result is simply due to the fact that the TED values are constant, but it is still important from a practical viewpoint. Namely, this proportional relationship and its slope are called the chemical dose-rate effect and the thermal line, respectively [16]. Where the DED value begins to become inclined, it represents quasi "equal dose equal damage" behavior [28,29].…”
Section: Simulation Of the Dose To Equivalentmentioning
confidence: 99%
“…Equation (16) shows that a T can be estimated to understand the temperature effect on the chemical reaction and the TED values by taking 1/T -1/T ref as a temperature parameter, even in this situation.…”
Section: Degradation Phenomena In Wide Temperature Rangesmentioning
confidence: 99%
“…Various degradation phenomena have been investigated for polymeric insulating materials exposed to both heat and radiation [14][15][16]. Containment is determined in terms of these two degradation factors, and the average temperature and radiation dose rate are approximately 50 °C and ~10 -3 Gy/h, respectively [14].…”
A new degradation model for safety cables in nuclear power plants that incorporates the critical antioxidant concentration concept is proposed in order to account for the effect of antioxidants and to simulate several synergisms in various thermal and radiation environments. A chemical reaction scheme is used to represent oxidation reactions via the decomposition of peroxide radicals. The effects of antioxidants are included in this scheme in order to demonstrate critical concentration phenomena. In addition, diffusion equations are added to the reaction rate equations to enable reproduction of diffusion-limited oxidation. Such a degradation model with antioxidant effects is discussed for degradation behaviors in polymers used for safety cables under various dose rates and temperature conditions, and its effectiveness is verified.
“…As shown in Table I, various radio-oxidation effects have been clarified and the findings have been reflected to type test procedures. Temperature effects are still assumed to fit to Arrhenius law, but recently, some results recommends to consider its non-linear phenomena called 'non-Arrhenius behaviors' [5], [26]. This requires to bend the extrapolation line in Arrhenius plots to predict long-term aging conservative than the traditional way.…”
Section: Road Map To Develop Degradation Prediction Model and Othmentioning
confidence: 99%
“…This is important not only for the model sophistication, but also for the development of CBQ. As for the acceleration aging, so-called 'wear-out approach' has been proposed recently [26]. This applies additional artificial aging on deposit or used cables to highlight their aging, and their aging status in service are estimated by back calculation.…”
Polymeric insulating materials used for safety-related cables in nuclear power plants are subject to thermal and radiation environment. The durability of such materials has been preserved through environmental qualification, but recently it also becomes necessarily to develop condition monitoring methods for aging management programs in order to adjust to plant life management. Such activities require some existing technologies to be re-validated. Understanding the degradation phenomena and long-term degradation prediction are found to be prime important in the following two kinds of points; i.e., view unification on type tests and technology development in condition monitoring. The present research completed a correlation map and a road map for element issues that still need to be solved.
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