Review of hydrogen storage techniques for on board vehicle applications

Durbin, D. J.; Malardier-Jugroot, Cécile

doi:10.1016/j.ijhydene.2013.07.058

Cited by 736 publications

(307 citation statements)

References 55 publications

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“…Among its benefits, hydrogen is the chemical fuel with the highest energy density by weight (after uranium and thorium), having a value of 142 MJ kg -1 , which is about three times more energy than gasoline and seven times more than coal per unit mass [5][6][7]. Furthermore, hydrogen can be obtained from water, a very abundant resource, which is more readily accessible than fossil fuels.…”

Section: Introductionmentioning

confidence: 99%

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Structure–property relationships in metal-organic frameworks for hydrogen storage

Noguera-Díaz

Bimbo

Holyfield

et al. 2016

Colloids and Surfaces A: Physicochemical and Engineering Aspect

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Experimental hydrogen isotherms on several metal-organic frameworks (IRMOF-1, IRMOF-3, IRMOF-9, ZIF-7, ZIF-8, ZIF-9, ZIF-11, ZIF-12, ZIF-CoNIm, MIL-101 (Cr), NH2-MIL-101 (Cr), NH2-MIL-101 (Al), UiO-66, UiO-67 and HKUST-1) synthesized in-house and measured at 77 K and pressures up to 18 MPa are presented, along with N2 adsorption characterization. The experimental isotherms together with literature high pressure hydrogen data were analysed in order to search for relationships between structural properties of the materials and their hydrogen uptakes. The total hydrogen capacity of the materials was calculated from the excess adsorption assuming a constant density for the adsorbed hydrogen. The surface area, pore volumes and pore sizes of the materials were related to their maximum hydrogen excess and total hydrogen capacities. Results also show that ZIF-7 and ZIF-9 (SOD topology) have unusual hydrogen isotherm shapes at relatively low pressures, which is indicative of "breathing", a phase transition in which the pore space increases due to adsorption. This work presents novel correlations using the modelled total hydrogen capacities of several MOFs. These capacities are more practically relevant for energy storage applications than the measured excess hydrogen capacities. Thus, these structural correlations will be advantageous for the prediction of the properties a MOF will need in order to meet the US Department of Energy targets for the mass and volume capacities of on-board storage systems. Such design tools will allow hydrogen to be used as an energy vector for sustainable mobile applications such as transport, or for providing supplementary power to the grid in times of high demand.

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Section: Introductionmentioning

confidence: 99%

“…They are usually synthesized using solvothermal methodologies at relatively mild conditions. Due to the crystallinity of these materials, powder X-ray diffraction can be used as an effective technique to determine the success of the synthesis [7,12].…”

Section: Introductionmentioning

confidence: 99%

Structure–property relationships in metal-organic frameworks for hydrogen storage

Noguera-Díaz

Bimbo

Holyfield

et al. 2016

Colloids and Surfaces A: Physicochemical and Engineering Aspect

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“…The density of hydrogen at the temperature T = 273 K and the pressure P = 1 atm is d = 0.0899 g/L equivalent to 8.99.10 -5 g/cm3 [1]. Numerous storage means have been envisaged for hydrogen and are currently competing: gas storage under ASTESJ ISSN: 2415-6698 pressure, cryogenic storage in liquid form, solid storage in hydrides and adsorbent materials [2].…”

Section: Introductionmentioning

confidence: 99%

Complete Modeling of the Hydrogen Stored in a Spherical Cavity

Idris-Bey¹,

Makridis²

2018

Adv. sci. technol. eng. syst. j.

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Hydrogen is the lightest of gases and possesses the lowest density. However at ambient temperature and pressure it occupies a large volume. This necessitates compressing it at high pressures up to 800 Bars to minimize the volume. The immense interest generated by hydrogen comes from the fact that it has the best energy per weight ratio of all fuels and the ecological nature of the combustion product. From the pedagogical point of view, it is also the most taught and involved in research, in particular in quantum mechanics. This aspect is treated in this article in order to

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“…Compared to the gas-and/or liquid-state hydrogen storage, the storage of hydrogen in solid state based on the physical or chemical interaction between hydrogen and hydrogen storage materials usually has a higher hydrogen density. Among the developed hydrogen storage materials, the metal aluminum hydrides such as LiAlH 4 , NaAlH 4 and Mg(AlH 4 ) 2 are some of the most promising candidates for the on-board hydrogen storage owing to their high hydrogen capacity [1][2][3][4][5][6] . For example, Liu et al found that the Ti-doped LiAlH 4 can release 7 wt.% of hydrogen commencing at temperature as low as 80 °C, and that the dehydrogenated product can be re-hydrogenated almost completely under 100 bar of hydrogen and room temperature by employing liquid Me 2 O as a solvent 3 .…”

Section: Introductionmentioning

confidence: 99%

“…To destabilize the Li-N-H system, Li was partially substituted by Mg or Ca, and the ternary Li-Mg-N-H [11][12][13][14][15][16][17] and Li-Ca-N-H 18-20 hydrogen storage systems were developed. Moreover, the combined alkali metal aluminum hydride-metal amide systems such as LiAlH 4 -LiNH 2 [21][22][23][24] , Li 3 AlH 6 -LiNH 2 25,26 , LiAlH 4 -Mg(NH 2 ) 2 27 and Na 2 LiAlH 6 -Mg(NH 2 ) 2 28 were intensively studied. However, the metal-N-H systems consisting of alkaline-earth metal aluminum hydride and metal amide were rarely reported.…”

Section: Introductionmentioning

confidence: 99%

Thermal Dehydrogenation Characteristics of Li-Sr-Al-N-H Hydrogen Storage System

Zhang

et al. 2017

Mat. Res.

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Thermolysis behavior of the Li-Sr-Al-N-H hydrogen storage system prepared by ball milling of Sr 2 AlH 7 + LiNH 2 mixture was investigated in this paper. The results show that thermal decomposition of the Li-Sr-Al-N-H system proceeds mainly in two steps with only hydrogen desorption. The thermal stability of this system is lowered as compared to the individual starting material, resulting in the hydrogen desorption initiating from about 125 °C. In addition, about 0.91 and 1.53 wt.% of hydrogen can be isothermally desorbed within 180 min at 180 and 330 °C, respectively. The decreased thermal stability of the Li-Sr-Al-N-H system might be attributed to the chemical reactions between the starting materials during the heating process with the formation of LiSrH 3 and N-containing amorphous phases.

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Review of hydrogen storage techniques for on board vehicle applications

Cited by 736 publications

References 55 publications

Structure–property relationships in metal-organic frameworks for hydrogen storage

Structure–property relationships in metal-organic frameworks for hydrogen storage

Complete Modeling of the Hydrogen Stored in a Spherical Cavity

Thermal Dehydrogenation Characteristics of Li-Sr-Al-N-H Hydrogen Storage System

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