Review and Outlook of Confined Ni Catalysts for the Dry Reforming of Methane Reaction

Abstract

Dry reforming of methane (DRM) transforms greenhouse gases of CH 4 and CO 2 to syngas of H 2 and CO, which conduces to reducing emissions of the greenhouse gases and producing sustainable energy chemicals. Catalysts with confined structures can actively and stably catalyze DRM owing to their unique properties of the confinement effect, metal−support interaction, size effect, etc. The properties significantly contribute to resolve the problems of metal sintering and carbon deposition in DRM. This review summarizes the latest developments of confined Ni catalysts for DRM in recent years. The synthetic approaches of the confined catalysts are first introduced, followed by the achievements of DRM over Ni@M 1 O x (M 1 O x = SiO 2 , Al 2 O 3 , and ZrO 2 ), Ni@zeolite (zeolite = SBA-15, MCM-41, and ZSM-5), bimetallic Ni−M 2 @SiO 2 (M 2 = Cu, In, and Co), and multifunctional (Ni/M 3 O x )@SiO 2 (M 3 O x = CeO 2 , ZrO 2 , and Mg phyllosilicate). After illustration of the mono-and bifunctional mechanisms, the remarks and perspectives of DRM are proposed in the end. The review will shed light on fabricating other new confined catalysts for DRM and other reactions.

Smart Designs of Zeolite-Based Catalysts for Dry Reforming of Methane: A Review

“…Meanwhile, the effective synthesis methods include a solvothermal polyol process, citric acid-assisted one-pot process, reversed microemulsion, and hard template. Notably, the combination of advanced technology will be supportive, such as electrospinning and microwave …”

“…For example, microwave irradiation promotes CH 4 activation with a low carbon production. Alternatively, the activation energy of the DRM process is significantly reduced under photothermal conditions . The incorporation of these methods is promising owing to the mild synthesis and reaction environments.…”