Reversible Sulfur Poisoning of 3-way Catalyst linked with Oxygen Storage Mechanisms

Koltsakis, G. C.; Alexiadou, Panagiota; Avgerinos, Christos; Symeonidis, Nikolaos; Nagano, Shota; Lafossas, F.-A.

doi:10.4271/2021-24-0069

Cited by 1 publication

(1 citation statement)

References 13 publications

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“…The main compounds formed by the contaminants at the TWC operational conditions are phosphates (AlPO 4 , Zn 2 P 2 O 7 ) [56], sulphates (Ce 2 (SO 4 ) 3 , CeOSO 4 ) [57,58] and oxides, with the sulphates being the primary contributing factors for the loss of catalyst activity [59]. Studies have shown that sulphur poisoning in TWC affects the ceria-related functions of the catalyst, namely the oxygen storage capacity and hydrogen formation from water gas shift and steam reforming pathways [60]. Under rich conditions, there are indications that H 2 S can poison the PGMs by the formation of sulphides [59].…”

Section: Three-way Catalystmentioning

confidence: 99%

Catalytic NOx Aftertreatment—Towards Ultra-Low NOx Mobility

Sandhu,

Yu,

Zheng

2024

IJAMM

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Article Catalytic NOx Aftertreatment—Towards Ultra-Low NOx Mobility Navjot Sandhu * , Xiao Yu, and Ming Zheng Department of Mechanical, Automotive and Materials Engineering, University of Windsor, 401 Sunset Avenue, Windsor, ON N9B 3P4, Canada * Correspondence: sandh12p@uwindsor.ca Received: 26 January 2024 Accepted: 13 March 2024 Published: 20 March 2024 Abstract: The push for environmental protection and sustainability has led to strict emission regulations for automotive manufacturers as evident in EURO VII and EPA2027 requirements. The challenge lies in maintaining fuel efficiency and simultaneously reducing the carbon footprint while meeting future emission regulations. Nitrogen oxides represent one of the major and most regulated components of automotive emissions. The need to meet the stringent requirements regarding NOx emissions in both SI and CI engines has led to the development of a range of in-cylinder strategies and after-treatment techniques. In-cylinder NOx control strategies including charge dilution (fresh air and EGR), low-temperature combustion, and use of alternative fuels (as drop-in replacements or dual fuel operation) have proven to be highly effective in thermal NOx abatement. Aftertreatment methods are required to further reduce NOx emissions. Current catalytic aftertreatment systems for NOx mitigation in SI and CI engines include the three-way catalyst (TWC), selective catalytic reduction (SCR) and lean NOx trap (LNT). This review summarizes various approaches to NOx abatement in IC engines using aftertreatment catalysts. The mechanism, composition, operation parameters and recent advances in each after-treatment system are discussed in detail. The challenges to the current after-treatment scenario, such as cold start light off, catalyst poisoning and the limits of current aftertreatment solutions in relevance to the EURO VII and 2026 EPA requirements are highlighted. Lastly, recommendations are made for future aftertreatment systems to achieve ultra-low NOx emissions.

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