“…Generally, the R-phase is seen in compositions with slightly higher nickel content, typically above Ti-50.5at%Ni (Khalil Allafi et al 2002;Khalil-Allafi et al 2002), and can be induced with proper heat treatment and the formation of precipitate structures (Cong et al 2014;Wang, Verlinden, et al 2015;Wang, Kustov, et al 2015). Studies on NiTi compositions of lower nickel content suggest that the R-phase transformation can be induced through a combination of heat treatment and material processing, such as cold working (Mahmud et al 2008;Okamoto et al 1988;Todoroki 1985;Todoroki & Tamura 1986;Goo & Sinclair 1985). It has also been proposed that grain sizes below 150 nm in Ni-rich NiTi can impede the formation of precipitate structures in NiTi (Prokofiev et al 2010).…”