Reversible Addition-Fragmentation Chain-Transfer Polymerization for the Synthesis of Poly(4-acetoxystyrene) and Poly(4-acetoxystyrene)-block-polystyrene by Bulk, Solution and Emulsion Techniques

Experimental Requirements for an Efficient Control of Free‐Radical Polymerizations via the Reversible Addition‐Fragmentation Chain Transfer (RAFT) Process

“…. [181] EAA a) [182] EEA a) [182] EOHMA [183] SPP a) [184] DBI [78] DCHI [78] MASASP [160] MBAm [249] AN [296,297] a) [72,110] (p-MeO)Ph-MMA [124,127] Sty [127] MA [73] StyOCOMe [240] BA [127] (p-CN)Ph-MMA [124] MA [73] (m-CF 3 )PhStyOCOMe [240] (p-F)Ph-MMA [124] Sty [127] MA [251] BA [127] (p-Ph)Ph-MMA [124] Sty [127] BA [127] …”

“…e) R 0 can be either H, alkyl, a-D-glucose, [351] hydroxypropyl cellulose, [351] b-cyclodextrin, [349,351] a branched polyester, [350] a dendrimer, [352] poly(dimethylsiloxane), [354] poly(DL-lactide), [355] or a Merrifield resin. [300] [374] StyOCOMe [240] Et 2 NSty [9,67,69,374] MA [192,375] VAc [67,376] EA [376] VAGlu [331] Sty [376] EA [376] VAc [376] StyOCOMe [240] EA [376] VAc [67] EA [376] Ph 2 N-EA [376] VAc [376] StyOCOMe [240] EA [376] Sty [9,69] AA [76] VDO [76] MA [67] NIPAm [377] DAAm [76] EA [376] [376] MMA [376] Sty [376] EA [376] VAc [376] Sty [376] Sty [376] MMA ...…”

“…When the nature of the two blocks is similar, the choice of the sequence is less crucial. Each block can be synthesized [9,67,119,356] BMA b) [151] EHMA b) [151] Sty [119] b) [151,229] MA [356] VAc [67] -C(Me) 2 CO 2 R 0d) Sty [356]c) [234] NIPAm c) [281] DMAm [343] -C(Me) 2 CO 2 CH 2 CH 2 C 6 F 13 MMA [113] -C(Me) 2 CONHC 18 H 37 NIPAm [347] -C(Me) 2 CONHCH 2 CH 2 OH MMA [119] -C(Me) 2 CONHCH 2 CH 2 SO 3 H MAETMAC [160] VPPS [160] MAm [160] DMAPMAm [160] MSASP [160] -C(Me)(SPh)CO 2 Et Sty [19,316] MA [19] -C(Me)(CO 2 Et) 2 AA [248] NAM [43] -C(Me) 3 MMA [9,119] Sty b) [230] AA [248] VC 2 a) [256] StyOCOMe [240] MA a) [256] BA [387] tBA [262] NAS a) [265][266][267][268][269][270][271] DMAm …”

“…d) R 0 can be poly(ethylene glycol) (PEG), [212,276] cellulose, [222] a polyester dendrimer, [221] a polypeptide, [260] or a silica nanoparticle. [217] [9,117,119,324,361] HEMA a) [348] NMAS [76] Sty [9,48,49,67,69,82,84, 107,110,119,133,186, 193,195,197,198,206, 213,216,298,311,324, 336,337,349-352, 361-365, 374,378, 382] a) [225 -227,348] b) [70,71,389] c) [300] MeSty a) [226] StyOCOMe [240] StyMe a) [226] StyOMe a) [226] StyCl a) [226] StyCH 2 Cl [216] StyCH 2 N(Me) 3 Cl [238] 4VP [364] AA [248,323, 366 -370] MA [67,73,119,192,324,336,337,[361][362][363]374,375,383] a) [256,335,379] c) [300] BA <...>…”

Controlled/Living Radical Polymerization in Aqueous Miniemulsion

“…RAFT miniemulsion polymerization has been recently reviewed by Zetterlund and co-workers [10] and by Cunningham [7]. In addition, numerous papers have appeared reporting on the RAFT miniemulsion of a large range of monomers such as: styrene [126][127][128][129][130][131][132][133][134] [ [135][136][137][138][139][140][141][142][143][144],4-acetoxystyrene [145],MMA [135,138,142,[146][147][148],EHMA [129,136], nBMA [129,136,147,[149][150][151], nBA [127,128,141,152,153], MAA [153], fluorinated alkyl methacrylates [149,151], acrylamide (inverse RAFT miniemulsion) [125], VAc [154,…”