1990
DOI: 10.1016/0166-6622(90)80175-4
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Reverse hemimicelle formation of 1-decanol from heptane at the solution/graphite interface

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Cited by 33 publications
(29 citation statements)
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“…At equilibrium this can be described by the following equation: For the adsorption of non-ionic surfactants from aqueous solutions on a porous surface (i.e., silica gels) the adsorption isotherm exhibits a sigmoidal shape (S-shape) as shown by several studies [19,27,28]. Moreover, Zhu and co-workers found that their two-step model with S-shape is also applicable to non-polar organic solvent [29]. For instance, this statement is consistent with calorimetric data according to the investigation of Findenegg et al on adsorption of decan-1-ol from heptane at solution/graphite interface [30].…”
Section: Zhu and Gu's Adsorption Modelmentioning
confidence: 93%
“…At equilibrium this can be described by the following equation: For the adsorption of non-ionic surfactants from aqueous solutions on a porous surface (i.e., silica gels) the adsorption isotherm exhibits a sigmoidal shape (S-shape) as shown by several studies [19,27,28]. Moreover, Zhu and co-workers found that their two-step model with S-shape is also applicable to non-polar organic solvent [29]. For instance, this statement is consistent with calorimetric data according to the investigation of Findenegg et al on adsorption of decan-1-ol from heptane at solution/graphite interface [30].…”
Section: Zhu and Gu's Adsorption Modelmentioning
confidence: 93%
“…In this model, two steps are considered for asphaltene adsorption. The first adsorption step is taken as the adsorption of asphaltenes in solution to the surface of the rock, and the second adsorption step is taken as the adsorption of asphaltenes in solution to those asphaltenes already adsorbed to the rock, as follows [31]:…”
Section: Asphaltene Adsorption and Deposition Modelsmentioning
confidence: 99%
“…A particularly common occurrence is what appears to be a two-rate type process, where a fast initial adsorption step is followed by a slower stage of adsorption before equilibrium is reached. This is generally not explained by any of the 'traditional' isotherms listed above, and so a range of new models have arisen in the last few decades in an attempt to provide a physical rationalization for the behavior seen [6][7][8][9][10][11][12][13]. Typically, the two-rate adsorption behavior can be a result of four possibilities (or a combination of them) -two-sites with different energies [14][15][16][17][18], two species with different adsorption rate constants (or diffusion coefficients) [19], rearrangement of adsorbed molecules on the surface [20][21][22][23] or bilayer adsorption [24][25][26][27][28].…”
Section: Introductionmentioning
confidence: 97%