Revealing the Limits of Intermolecular Interactions: Molecular Rings of Ferrocene Derivatives on Graphite Surface

Abstract

We report the formation of discrete molecular rings/spirals of small molecules (1,3-dithia derivatives of ferrocene) on a highly oriented pyrolytic graphite (HOPG) surface. On the basis of microscopy and theoretical calculations, molecular level arrangement within the molecular rings is understood. The molecular rings show a limiting inner diameter, and we interpret it to be related to the critical intermolecular interaction limit. This limiting value of the inner diameter is surprisingly correlated with that observed for molecular rings/disks of a few reported molecules. The correlation reveals that molecular rings formed typically by weak van der Waals interactions should always show a limiting inner diameter and should be independent of molecular structure, size, and chemical nature.

Supramolecular double-stranded Archimedean spirals and concentric toroids

“…7). As such, the self-assembly process of 6FF is distinctly different from those of other supramolecular spirals reported in the literatures, which required the presence of 2D self-assembly fields, such as substrate surfaces or an air-water interface [28][29][30][31][32] . When we tested other solvents, we found that the spiral structures tended to form in linear alkanes, such as hexane or dodecane ( Supplementary Fig.…”