the experiments were carried on the treatment of Ethylenediamine (EDA) wastewater by supercritical water oxidation (SCWO). The effect of factors including reaction temperature, pressure, residence time and O 2 stoichiometric ratio on the EDA decomposition were studied. And the radical reaction mechanism was used to explain the decomposition process of EDA by SCWO. The results found that SWCO can destruct the organic compounds in EDA wastewater into CO 2 and N 2 . With increasing of reaction temperature, pressure, residence time, and decreasing of initial TOC concentration, TOC conversion increased. When the O 2 stoichiometric ratio is below 1.5, the change of O 2 stoichiometric ratio could influence the TOC conversion significantly. When the reaction temperature is above 535 ℃ and residence time is over 120 s, the TOC conversion of EDA is above 98%.