RETRACTED ARTICLE: A Highly Porous Co-MOF for Cyanosilylation Reaction and Inhibition on P. gingivalis Growth and rgp and kgp Expression for Periodontal Treatment

Improved Performance of a Europium‐based Metal‐Organic Framework for Cyanosilylation of Demanding Ketones

“…[15] This reaction was firstly reported in 1994 by Fujita and coworkers using a Cd-MOF catalyst, [17] and here after, a plethora of diverse works have been applied to this specific reaction using metal-MOF such as based on Cu, Cr, Mn, Fe, Co, Zr, etc. [18][19][20][21][22][23][24] Placing the focus on lanthanide-based MOFs, no more than 15 examples have been reported so far, where the catalytic activity of the material is demonstrated by using catalyst loadings in the range of 1 to 10 mol%, and using in all of them reactive aldehydes as electrophiles. [25][26][27][28][29][30][31][32][33][34][35][36][37][38] There are only three examples where the use of less reactive ketones was studied with these rare-earth metal-MOFs giving rise to the formation of highly interesting quaternary centers.…”

“…In recent years, various studies have been conducted towards the use of rare‐earth MOFs as heterogeneous catalysts for organic reactions, being one of these benchmark transformations the cyanosilylation of carbonyl‐containing compounds [15] . This reaction was firstly reported in 1994 by Fujita and coworkers using a Cd‐MOF catalyst, [17] and here after, a plethora of diverse works have been applied to this specific reaction using metal‐MOF such as based on Cu, Cr, Mn, Fe, Co, Zr, etc [18–24] . Placing the focus on lanthanide‐based MOFs, no more than 15 examples have been reported so far, where the catalytic activity of the material is demonstrated by using catalyst loadings in the range of 1 to 10 mol%, and using in all of them reactive aldehydes as electrophiles [25–38] .…”