Reticular chemistry guided precise construction of zirconium-pentacarboxylate frameworks with 5-connected Zr<sub>6</sub> clusters

Peng, Tianyou; Han, Chao-Qin; Xia, Hai-Lun; Zhou, Kang; Zhang, Jian; Si, Jincheng; Wang, Lei; Miao, Jiafeng; Guo, Fu-An; Wang, Hao; Qu, Lu-Lu; Xu, Guozhong; Li, Jing; Liu, Xiao-Yuan

doi:10.1039/d3sc05410a

Chem. Sci.

2024

DOI: 10.1039/d3sc05410a

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Reticular chemistry guided precise construction of zirconium-pentacarboxylate frameworks with 5-connected Zr₆ clusters

Tianyou Peng,

Chao-Qin Han,

Hai-Lun Xia

et al.

Abstract: Zirconium-based metal-organic frameworks (Zr-MOFs) have been extensively studied due to their very rich structural chemistry. The combination of nearly unlimited carboxylic acid-based linkers and Zr6 clusters with multiple connectivities has...

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Reticular Chemistry Directed “One‐Pot” Strategy to in situ Construct Organic Linkers and Zirconium‐Organic Frameworks

Han,

Wang,

et al. 2024

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Zirconium‐based metal–organic frameworks (Zr‐MOFs) have emerged as one of the most studied MOFs due to the unlimited numbers of organic linkers and the varying Zr‐oxo clusters. However, the synthesis of carboxylic acids, especially multitopic carboxylic acids, is always a great challenge for the discovery of new Zr‐MOFs. As an alternative approach, the in situ “one‐pot” strategy can address this limitation, where the generation of organic linkers from the corresponding precursors and the sequential construction of MOFs are integrated into one solvothermal condition. Herein, inspired by benzimidazole‐contained compounds synthesized via reaction of aldehyde and o‐phenylenediamine, tri‐, tetra‐, penta‐ and hexa‐topic carboxylic acids and a series of corresponding Zr‐MOFs can be prepared via the in situ “one‐pot” method under the same solvothermal conditions. This strategy can be utilized not only to prepare reported Zr‐MOFs constructed using benzimidazole‐contained linkers, but also to rationally design, construct and realize functionalities of zirconium‐pentacarboxylate frameworks guided by reticular chemistry. More importantly, in situ “one‐pot” method can facilitate the discovery of new Zr‐MOFs, such as zirconium‐hexacarboxylate frameworks. The present study demonstrates the promising potential of benzimidazole‐inspired in situ “one‐pot” approach in the crystal engineering of structure‐ and property‐specific Zr‐MOFs, especially with the guidance of reticular chemistry.

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Reticular Chemistry Directed “One‐Pot” Strategy to in situ Construct Organic Linkers and Zirconium‐Organic Frameworks

Han,

Wang,

et al. 2024

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Reticular chemistry guided single-linker constructed pillar-layered metal–organic frameworks via an in situ “one-pot” strategy

Ma,

Yang,

Xing

et al. 2024

Dalton Trans.

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Reticular chemistry guided precise construction of zirconium-pentacarboxylate frameworks with 5-connected Zr₆ clusters

Abstract: Zirconium-based metal-organic frameworks (Zr-MOFs) have been extensively studied due to their very rich structural chemistry. The combination of nearly unlimited carboxylic acid-based linkers and Zr6 clusters with multiple connectivities has...

Cited by 2 publications

References 59 publications

Reticular Chemistry Directed “One‐Pot” Strategy to in situ Construct Organic Linkers and Zirconium‐Organic Frameworks

Reticular Chemistry Directed “One‐Pot” Strategy to in situ Construct Organic Linkers and Zirconium‐Organic Frameworks

Reticular chemistry guided single-linker constructed pillar-layered metal–organic frameworks via an in situ “one-pot” strategy

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Reticular chemistry guided precise construction of zirconium-pentacarboxylate frameworks with 5-connected Zr6 clusters

Abstract: Zirconium-based metal-organic frameworks (Zr-MOFs) have been extensively studied due to their very rich structural chemistry. The combination of nearly unlimited carboxylic acid-based linkers and Zr6 clusters with multiple connectivities has...

Cited by 2 publications

References 59 publications

Reticular Chemistry Directed “One‐Pot” Strategy to in situ Construct Organic Linkers and Zirconium‐Organic Frameworks

Reticular Chemistry Directed “One‐Pot” Strategy to in situ Construct Organic Linkers and Zirconium‐Organic Frameworks

Reticular chemistry guided single-linker constructed pillar-layered metal–organic frameworks via an in situ “one-pot” strategy

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Reticular chemistry guided precise construction of zirconium-pentacarboxylate frameworks with 5-connected Zr₆ clusters