The perovskites of La2/3Ca1/3MnO3 (LCMO) and
La2/3Sr1/3MnO3 (LSMO) were synthesized by the sol-gel
method. The two perovskites were mixed into polycrystalline materials,
(1-m)LCMO + mLSMO, where m is the relative weight ratio of
LSMO. The compound with m~0.3-0.5 has the lowest
semiconductor-metal transition temperature Tp and the largest
low-T resistivity. Moving away from this ratio, Tp increases
while the low-T resistivity decreases with increasing or
decreasing m. Measurements of the magnetoresistance (MR) show that
the mixed polycrystals exhibit a sizable MR effect in low magnetic
fields which increases upon cooling and reaches its largest value for
T→0 K. It is also interesting to observe the almost
T-independent MR effect over a wide temperature window below 300 K
for the mixed materials with smaller m.