2010
DOI: 10.1021/cm1019684
|View full text |Cite
|
Sign up to set email alerts
|

Resorcinol-Based Deep Eutectic Solvents as Both Carbonaceous Precursors and Templating Agents in the Synthesis of Hierarchical Porous Carbon Monoliths

Abstract: Deep eutectic solvents are a new class of ionic liquids obtained via the complexion of quaternary ammonium salts with hydrogen-bond donors (such as acids, amines, and alcohols, among others). The charge delocalization that occurs through hydrogen bonding between the halide anion with the hydrogendonor moiety is responsible for the decrease in the freezing point of the mixture, relative to the melting points of the individual components. We have recently reported on the use of deep eutectic solvents as suitable… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
1
1
1
1

Citation Types

4
113
0
1

Year Published

2012
2012
2019
2019

Publication Types

Select...
5
4
1

Relationship

1
9

Authors

Journals

citations
Cited by 148 publications
(121 citation statements)
references
References 52 publications
4
113
0
1
Order By: Relevance
“…Ionic liquids are established precursor compounds in the field of materials chemistry, [19][20][21][22][23] but just recently they have been applied as precursors for nitrogen-doped carbon. [24][25][26][27][28][29] As liquids with negligible vapour pressure, such precursors can be easily processed and transformed into N-doped carbon materials by simple annealing under inert gas atmosphere.…”
Section: -8mentioning
confidence: 99%
“…Ionic liquids are established precursor compounds in the field of materials chemistry, [19][20][21][22][23] but just recently they have been applied as precursors for nitrogen-doped carbon. [24][25][26][27][28][29] As liquids with negligible vapour pressure, such precursors can be easily processed and transformed into N-doped carbon materials by simple annealing under inert gas atmosphere.…”
Section: -8mentioning
confidence: 99%
“…IL based syntheses of carbon materials have been established in manifold ways in recent years of research. [1][2][3][4][5][6][7][21][22][23][39][40][41][42][43][44][45][46][47][48] Especially liquid salts with dicyanamide anions are a powerful precursor for N-doped carbons, [1][2][3][4][5][6][7] and for advanced co-doping with S. 27 Herein we present a modified IL route using phosphonium additives, paving the way towards P-and N-co-doped carbonsa class of materials only rarely reported in the literature so far. 36 BMP-dca with 40 mol% of tetrabutyl-phosphonium-bromide (TBuPBr) as a phosphorus source was therefore carbonised at 1000 1C in a constant flow of inert gas (see ESI † for details).…”
mentioning
confidence: 99%
“…2.1) that, upon polycondensation with formaldehyde, resulted in the formation of monolithic carbons with a bimodal porosity that comprises both micropores and large mesopores of ca. 10 and 23 nm, respectively [64]. The morphology of the resulting carbons consisted of a bicontinuous porous network built of highly cross-linked clusters that aggregated and assembled into a stiff, interconnected structure.…”
Section: Use Of Dess In the Synthesis Of Porous Carbon Materialsmentioning
confidence: 99%