There have been predictions that for closely spaced two-dimensional electron gases ͑2DEG's͒, charge transfer between the 2DEG's can arise from electron interactions due to exchange and correlation ͓Ruden and Wu, Appl. Phys. Lett. 59, 2165 ͑1991͔͒. In this study, we are able to determine accurately the charge in each of the 2DEG's of a triple-quantum-well structure. The results demonstrate that as the charge in one 2DEG is reduced, by applying a negative gate voltage the adjacent layer can gain charge; thus charge is effectively transferred between the 2DEG's. This type of charge transfer cannot be explained by a simple noninteracting model of the structure, but can be modeled by including intralayer electron interactions in the form of exchange and correlation correction terms within the local-density approximation. The inclusion of these many-body interaction terms into our model leads to a good qualitative agreement with the experimental data, confirming that the origin of the charge transfer is electron interactions.