Various combinations of periodically assembled nanoporous silicon layers with different refractive indices and thicknesses have been used to fabricate one-dimensional photonic quantum well structures, in which both the well and barrier regions consist of photonic crystals. The structures are operational in the regime of visible light. Quantized states resulting from the photonic confinement effect are observed, consistent with calculations using the transfer-matrix method. Behaviors of the photons in the structures can be well described by the effective wave-vector approach. It has been well established that, in analogy to the electrons in a quantum well (QW) or superlattice [1,2], the photons in a proper assembly of photonic crystals (PCs) with different band gaps are confined to quantized energy states, or referred to as being in a photonic quantum well structure (PQWS) [3 -10]. Early explorations in the millimeter-wave region gave rise to the emergence of two-and threedimensional PQWSs [3,4,9]. The transmissivity of a confined photonic state can be as high as unity, just like resonant tunneling of an electron through a semiconductor QW system. Obviously, the novel features of PQWSs are attractive for both fundamental and application studies.The simplest way to form a one-dimensional (1D) PQWS is to use a homogenous dielectric slab as the photonic well, sandwiched between two PCs as the photonic barriers [10]. But it is difficult to observe the photonic band gap (PBG) or QW effect in such a 1D PQWS and the structure arouses little interest actually [8]. Alternatively, a properly designed PC can be used as the well in a PQWS [7]. In that case, one may expect the QW effect observable and the number of the confined photonic states tunable by adjusting the number of the PC periods. This may lead to applications of the new structure in high-performance optoelectronic devices such as high-frequency PBG devices, multi-channel filters, etc. Further experimental investigation on the latter 1D PQWS is thus needed.In this communication, we report on realization of the structure by using porous silicon as the constituent material for all the PCs. The 1D PQWSs fabricated are operational in the regime of visible light and can be well described by the effective wave-vector approach [11,12] initially developed for description of the phonon confinement effect in the electronic QWs. The theoretically predicted [7] nonequivalence of the number of the confined photonic states with the photonic well periods in case that the photonic barrier does not completely confine a photonic band of the photonic well has also been experimentally confirmed.Exactly speaking, the porous silicon constituting the PCs studied in the present experiment is nanoporous silicon (nPSi) 1 , prepared by means of pulsed electrochemical etching [13]. Heavily doped (, 0.01 V cm) p-type Si (001) 0038-1098/03/$ -see front matter q 2003 Elsevier Science Ltd. All rights reserved. PII: S 0 0 3 8 -1 0 9 8 ( 0 2 ) 0 0 8 9 2 -X Solid State Communications 126...