Abstract:This work presents a complete vibrational analysis of iron [ Fe (II) and Fe (III)] and nickel [ Ni (II)] complexes with 5,10,15,20-tetraphenyl-21-oxaporphyrin [OTPPH] and 5,20-bis(p-tolyl)-10,15-diphenyl-21-oxaporphyrin [ODTDPPH]. In these porphyrins, a furan ring replaces one of the pyrrole rings. The six-coordinate (OTPP) FeIIICl2 and (ODTDPP) FeIIICl2 as well as the five-coordinate (OTPP) FeIICl and (OTPP) NiIICl complexes were investigated using experimental and theoretical methods. The experimental part o… Show more
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