2016
DOI: 10.1007/s10948-016-3851-1
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Resistivity in Cuprates and the Pseudogap

Abstract: The temperature dependence of resistivity (ρ) in the normal state of La 2−x Sr x CuO 4 is calculated from electron transfer (ET) rates. The minimum at about 100 K for doping levels less than 6 % is characteristic for all cuprates. The resistivity depends on ET between Cu(III) and Cu(II) sites. For T < 300 K, the resistivity is proportional to T 3/2 . The more than linear increase of ρ for T >100 K depends on increased kinetic energy in a Landau avoided crossing. The agreement with experimental data is convinci… Show more

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Cited by 2 publications
(2 citation statements)
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“…Two factors, activation loss (ϕact) and ohmic resistance loss (ϕom), contribute in different ways to this potential loss, preventing G. sulfurreducens from experiencing the poised anode potential (ϕanode) throughout the biofilm. Activation losses incur in the charge transfer of electrochemical reactions [14,63] , such as the transfer of electrons on the conductive biofilms (Cytred ⇌ Cytox+ e -), and from the biofilm onto the electrode (Rxn 2). The ohmic loss results from the electronic resistance on biofilms and at the electrode surface.…”
Section: Potential Losses Are the Dominant Factor Shaping The Distrib...mentioning
confidence: 99%
“…Two factors, activation loss (ϕact) and ohmic resistance loss (ϕom), contribute in different ways to this potential loss, preventing G. sulfurreducens from experiencing the poised anode potential (ϕanode) throughout the biofilm. Activation losses incur in the charge transfer of electrochemical reactions [14,63] , such as the transfer of electrons on the conductive biofilms (Cytred ⇌ Cytox+ e -), and from the biofilm onto the electrode (Rxn 2). The ohmic loss results from the electronic resistance on biofilms and at the electrode surface.…”
Section: Potential Losses Are the Dominant Factor Shaping The Distrib...mentioning
confidence: 99%
“…Взаимодействие электронов с решеткой, в частности, влияние на перенос электронов/дырок в купратах, подробно рассматривалось в работах Ларссона [20,21] в рамках стандартного квантово-химического подхода. Учет электронно-колебательного взаимодействия для одночастичного переноса заряда типа Cu 2+ − Cu 3+ → Cu 3+ − Cu 2+ в рамках полуклассической модели Маркуса [22] out-of-plane stuff", при котором U th обращается в нуль и система переходит в режим конденсации EH-димеров с полным диспропорционированием Cu 2+ − Cu 2+ → Cu 3+ − Cu 1+ (11 → 20 (02)).…”
Section: аномальная электрон-решеточная релаксация и Eh-димеры в купрunclassified