Research Progress in Non-noble Metals Catalyzed Hydroamination of Alkyenes and Alkynes<b />

Wang, Jian; Cui, Dongmei

doi:10.6023/cjoc201512010

Cited by 6 publications

References 27 publications
(29 reference statements)

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Organometallic Mn(I) Complexes in Asymmetric Catalytic (Transfer) Hydrogenation and Related Transformations
Fu,
Wang,
Liu
et al. 2024
ChemCatChem
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Direct asymmetric hydrogenation (AH) and asymmetric transfer hydrogenation (ATH) reactions are among the most efficient approaches to produce chiral building blocks. Recently, these types of transformations have witnessed a shift towards the use of molecular catalysts based on earth‐abundant transition metals due to their ready availability, economic advantage, and novel properties. With particular regard to manganese, catalyst development has seen both the efficiency and substrate scope in AH and ATH greatly improved, with the emergence of a large number of well‐defined Mn‐complexes employed in this field. The reaction scope includes the AH and ATH of C=O bonds, asymmetric reduction of C=N bonds and the asymmetric reductive transformations of C=C bonds. Herein, our survey of the area focuses on the catalytic activity of such complexes, their versatility towards asymmetric transformations and the routes employed to convert substrates to their target molecules. We consider the collected findings of this article will be helpful to the reader by providing an insight into ligand design, thereby aiding future catalyst development. Moreover, this review is aimed at highlighting the remarkable progress made in the last six years in the development of manganese complexes for enantioselective reduction.

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Organometallic Mn(I) Complexes in Asymmetric Catalytic (Transfer) Hydrogenation and Related Transformations
Fu,
Wang,
Liu
et al. 2024
ChemCatChem
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N -Alkyl Amine Synthesis by Hydroamination of Alkene and Diene
Shi¹,
Cui²
2018
Catalytic Amination for N-Alkyl Amine Synthesis
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Geometry, stability and aromaticity of β-diketiminate-coordinated alkaline-earth compounds
Li
¹
,
Chen
²
,
Qu
³

et al. 2019
Chinese Chemical Letters
10
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3
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Research Progress in Non-noble Metals Catalyzed Hydroamination of Alkyenes and Alkynes

Cited by 6 publications

References 27 publications

Organometallic Mn(I) Complexes in Asymmetric Catalytic (Transfer) Hydrogenation and Related Transformations

Organometallic Mn(I) Complexes in Asymmetric Catalytic (Transfer) Hydrogenation and Related Transformations

N -Alkyl Amine Synthesis by Hydroamination of Alkene and Diene

Geometry, stability and aromaticity of β-diketiminate-coordinated alkaline-earth compounds

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