Military vocational education is a continuing education for military personnel. It is an urgent task for military vocational education to cultivate a large number of new military talents with high quality. MOOC (Massive Open Online Course) provides a new means to promote the military vocational education, which will help to promote the formation of military vocational distance education system in our army. This paper discusses the connotation and characteristics of military vocational education, analyzes the MOOC teaching mode of military vocational education, and finally gives the corresponding countermeasures for developing MOOC teaching in military vocational education. In order to actively promote the development of information technology in military vocational education, new ideas and new ways are provided to effectively improve the quality of military personnel.