Piezoelectric composites will cause different degrees of deformation when ambient temperature changes during transportation, storage and use, affecting the performance and reliability seriously. The deformation measurement of cylindrical piezoelectric composites based on fiber Bragg grating (FBG) measurement is presented in this paper. The deformation and electromechanical properties of cylindrical piezoelectric composites over a wide range of temperature, from 233 K to 373 K, are investigated in detail. The deformation of piezoelectric composites in different directions is calculated. Adding deformation information, the frequency constant and dielectric constant data are modified. The results show that, at 233 K, the relative change of curvature of the cylindrical composite material in the arc direction is 0.024% and the relative change of deformation in the width and thickness direction are 0.018% and 0.026%, respectively. When the environment's temperature is increased to 100℃, the relative change of curvature in the arc direction is 0.019% and the relative changes of deformation in the width and thickness direction are 0.019% and 0.008%, respectively.After adding the deformation information, the most evident changes of frequency constant and dielectric constant are between 303 K and 333 K, the rate of change (slope) of frequency constant and the dielectric constant are −1.82983 kHz ⋅ mm∕K (decreasing) and 3.85591 kHz ⋅ mm∕K(increasing), respectively. K E Y W O R D S curved surface, piezoelectric composites, thermal properties 998 | HOU et al. F I G U R E 1 The schematic diagram of whole testing method. (A) Strain sensing principle of fiber Bragg grating; (B) The schematic diagram of fiber Bragg grating structure; (C) Cross sectional view of surface-bonded structure