Reproducibility challenges in activating two-dimensional polymers and three-dimensional covalent organic frameworks
Rupam Roy,
Austin M. Evans
Abstract:Two-dimensional polymers and three-dimensional covalent organic frameworks are crystalline, permanently porous macromolecules. Removing guest molecules from the pores of these materials reliably is challenging because extreme capillary forces are generated when evacuating nanoporous structures. Herein, we outline the most common approaches for isolating and activating these materials. We also note how some methods, such as thermal activation under vacuum, introduce significant challenges with reproducibly acti… Show more
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