“…By contrast, the equilibrium phase change assumption, which is often implemented in soil hydrology modeling, assumes that the time associated with volatilization or condensation is negligible [e.g., Philip and de Vries, 1957;Whitaker, 1977;Parlange et al, 1998;Grifoll et al, 2005;Zhang et al, 2005;Bittelli et al, 2008;Sakai et al, 2009;Novak, 2010]. Experimental evidence has shown that the assumption of local equilibrium may in fact be unsuitable under certain conditions [e.g., B enet and Jouanna, 1982;Armstrong et al, 1994;Ruiz and B enet, 2001;Chammari et al, 2003Chammari et al, , 2008Lozano et al, 2008;B enet et al, 2009;Lozano et al, 2009;Smits et al, 2011Smits et al, , 2012bOuedraogo et al, 2013]. Nonequilibrium conditions can be observed at low water saturations when soils are in hygroscopic moisture states, especially in clay and silt-rich soils [B enet and Jouanna, 1982;Ruiz and B enet, 2001;Chammari et al, 2003;Lozano et al, 2008].…”