Removing of cationic dyes using self-cleaning membranes-based PVC/nano-cellulose combined with titanium aluminate

Abstract

This research used the phase inversion approach to construct polyvinyl chloride nanocellulose@titanium aluminate nanocomposite membranes (PVC/NC@TALCM) to adsorb and filter dye from wastewater. FTIR, XRD, and SEM were used to determine the adsorptive nanocomposite membrane that had been synthesized. The thermal and electrical properties measurements were carried out using a static system. The influence of several adsorbent dosages, pH, and dye concentrations on the nanocomposite membrane’s adsorption ability was investigated. Using a dead-end filtration system, the PVC-NC@TALCM was evaluated as a pressure filtration membrane system. It was found that 98.6% of MB dye was removed by PVC-NC@TALCM membrane, which was loaded with 5% titanium aluminate at pH 10. The kinetic adsorption studies indicated that the adsorption of MB onto the PVC-NC@TALCM nanocomposite membrane obeys pseudo-second-order that indicates the chemosorption process. The isotherm data were described using Freundlich and Langmuir models, and the Freundlich isotherms were shown to be more closely match the experimental data than the Langmuir model. Finally, the PVC-NC@TALCM nanocomposite membrane was economical, environmentally friendly, and self-cleaning.