Removal of Methylene Blue from Aqueous Solution By Polydopamine@Zeolitic Imidazolate-67

Abstract

Herein, a facile and low-cost route was used to prepare Polydopamine@Zeolitic Imidazolate Framework-67 (PDA@ZIF-67). The structure, morphology, surface functional groups and particle size distribution of PDA@ZIF-67 were studied using FTIR, FESEM, EDS, and BET analyses. The specific surface area and diameter of ​​PDA@ZIF-67 were equal to be 78.203 m2/g and 4.179 mm, respectively. The PDA@ZIF-67 was used as an adsorbent for the adsorption of methylene blue dye. The results show that the maximum adsorption efficiency of methylene blue on the surface of PDA@ZIF-67 is achieved at pH 2, the temperature of 65°C, 10 mg of adsorbent, and methylene blue concentration of 7.5 ppm.Moreover, the adsorption process's isothermal, thermodynamic, and kinetics were studied entirely to consider the adsorption mechanism. The methylene blue molecules located in the fine pores of the PDA@ZIF-67 adsorbent determine the adsorption rate. Moreover, the adsorption process of methylene blue at high temperatures is a spontaneous and endothermic reaction. The adsorption efficiency of PDA@ZIF-67, after the recovery, reached 62.21%, which is an excellent advantage for using this adsorbent.

Optimizing methylene blue adsorption conditions on hydrothermally synthesized NaX zeolite through a full two-level factorial design

“…Then, at pH 4, an uptake ∼35% was determined, observing a slightly decreasing trend with increasing pH until reaching ∼27% at pH 12. These results were in line with published results on the MB adsorption onto different zeolites 47 and conrmed the signicance of pH on the adsorption of organic and inorganic pollutants on zeolitic materials. 48 The point of zero charge (pH pzc ) corresponds to a neutral surface charge.…”