Removal of Mercury Ions from Aqueous Solutions by Crosslinked Chitosan‐based Adsorbents: A Mini Review

Zhang, Dan; Crini, Grégorio; Lichtfouse, Éric; Rhimi, Baker; Wang, Chuanyi

doi:10.1002/tcr.202000073

Cited by 28 publications

(10 citation statements)

References 120 publications

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“…Among different biopolymers, chitosan (CN) is of natural origin and is prepared from the deacetylation of chitin of different crustacean shells. Chitosan exhibits three reactive functional groups named a primary amino group (C2-NH 2 ), a secondary hydroxyl group (C3-OH), and a primary hydroxyl group (C6-OH), which can chelate HMs [17,18]. Due to its robust metal chelation ability, CH has been widely used for in-situ immobilization of different HMs in metal-polluted soils, reduced uptake in food crops, and augmented their dietary worth [8,16].…”

Section: Introductionmentioning

confidence: 99%

Effects of Soil Application of Chitosan and Foliar Melatonin on Growth, Photosynthesis, and Heavy Metals Accumulation in Wheat Growing on Wastewater Polluted Soil

et al. 2022

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Due to freshwater scarcity in developing countries, irrigating the arable land with wastewater poses potential ecological risks to the environment and food quality. Using cheap soil amendments and foliar application of a newly discovered molecule “melatonin” (ML) can alleviate these effects. The objectives of this pot study were to evaluate the effectiveness of the sole addition of chitosan (CH) and sugar beet factory lime (SBL) in wastewater impacted soil, foliar application of ML, and combining each soil amendment with ML on the heavy metals (HMs) accumulation, growth, nutritional quality and photosynthesis in wheat. Results showed that CH was more effective than SBL for reducing HMs bioavailability in soil, HMs distribution in plants, improving photosynthesis, nutritional quality, and growth. ML application also influenced plant parameters but less than CH and SBL. The CH+ML treatment was the most effective for influencing plant parameters and reducing HMs bioavailability in the soil. Compared to control, CH+ML significantly reduced the concentrations of Pb, Cd, Cr, Ni, Cu, and Co in roots, shoots, and grain up to 89%. We conclude that adding CH+ML in wastewater impacted soils can remediate the soil; reduce HMs concentrations in plants; and improve their photosynthesis, plant growth, grain yield, and nutrition.

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Section: Introductionmentioning

confidence: 99%

Effects of Soil Application of Chitosan and Foliar Melatonin on Growth, Photosynthesis, and Heavy Metals Accumulation in Wheat Growing on Wastewater Polluted Soil

et al. 2022

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“…In literature reports, higher but inconsistent sorption capacities and removal efficiencies of mercury can be found, but sorption is mostly performed from modal solutions with significantly higher initial mercury concentrations [71,72]. Higher concentration usually leads to improved sorption capacity due to the greater driving force [73].…”

Section: Mercury Leaching From Contaminated Soil and Its Subsequent S...mentioning

confidence: 99%

Assessment of Natural Zeolite Clinoptilolite for Remediation of Mercury-Contaminated Environment

et al. 2022

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The soil at ancient roasting sites in the surroundings of the Idrija mine (Slovenia) is highly contaminated with mercury. To assess the impact of mercury on groundwater by infiltration and find an eco-friendly remediation method, the leaching of mercury from the soil containing 1347 mg Hg/kg, followed by sorption of the total leached mercury on cost-effective natural zeolite (NZ) clinoptilolite, was performed. The leaching of soil in ultrapure water of pHo = 3.00–11.46 after 24 h resulted in the total leached mercury concentration in the range 0.33–17.43 µg/L. Much higher concentrations (136.9–488.0 µg/L) were determined after the first few hours of leaching and were high above the maximum permissible level in water for human consumption. The NZ showed very good sorption of the total leached mercury, with a maximum removal efficiency of 94.2%. The leaching of mercury in presence of the NZ resulted in a significant decrease of the total leached mercury (1.9–20.3 µg/L compared to 12.8–42.2 µg/L), with removal efficiencies up to 90.5%, indicating immobilization of mercury species. The NZ has a great potential for economically viable remediation of mercury-contaminated environment. However, efforts should be made in the further study of mercury leachability to reduce the mercury concentration in water to acceptable levels.

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“…The existence of amine groups is indicated by the N-H stretching (3389.364 cm −1 ) in GKC. The amino (N-H) and hydroxyl (O-H) groups with H 2 bonding are the preferential groups for the CF process [44][45][46]. The medium C-H stretch (2883.547 and 3000.239 cm −1 ) and C-Cl (alkyl halides) stretch (828.92 cm −1 ) were present on the GKC.…”

Section: Sem and Ftir Characterisation Of The Gkcmentioning

confidence: 99%

Coagulation-Flocculation of Aquaculture Wastewater Using Green Coagulant from Garcinia kola Seeds: Parametric Studies, Kinetic Modelling and Cost Analysis

et al. 2021

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To achieve sustainability, it is necessary to use proper treatment methods to reduce the pollutant loads of receiving waters. This study investigates the coagulative reduction of turbidity, COD, BOD and colour from aquaculture wastewater (AW) using a novel Garcinia kola seeds coagulant (GKC). This coagulant was obtained from extraction of Garcinia kola seeds and analysed for its spectral and morphological characteristics through FTIR and SEM. The kinetics of coagulation-flocculation were also investigated in terms of total dissolved and suspended solids (TDSP). The seeds had 11.27% protein and 68.33% carbohydrate, showing usability in adsorption/charges neutralisation as a coagulant to reduce particles. Maximal turbidity reduction = 81.93%, COD = 75.03%, BOD = 72.84% and colour = 56.69% at 0.3 g GKC/L, pH 2, 60 min and 303 K were achieved. Von Smoluchowski’s second-order peri-kinetics theory was used to fit the results, giving R2 > 0.9. At a coagulation order (α) of 2, the reaction rate (KC) and half-life (τS1/2) were 0.0003 L/g·min and 25.3 min at the optimal conditions. The sorption data better fit the Lagergren compared to the Ho adsorption model. Furthermore, the net cost of using GKC to handle 1 L of AW (including electricity and material costs) was calculated to be 1.57 EUR, and the costs of 0.3 g/L GKC preparation and energy were 0.27 and 1.30 EUR, respectively. In summary, these seeds can be used to pre-treat AW.

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Removal of Mercury Ions from Aqueous Solutions by Crosslinked Chitosan‐based Adsorbents: A Mini Review

Cited by 28 publications

References 120 publications

Effects of Soil Application of Chitosan and Foliar Melatonin on Growth, Photosynthesis, and Heavy Metals Accumulation in Wheat Growing on Wastewater Polluted Soil

Effects of Soil Application of Chitosan and Foliar Melatonin on Growth, Photosynthesis, and Heavy Metals Accumulation in Wheat Growing on Wastewater Polluted Soil

Assessment of Natural Zeolite Clinoptilolite for Remediation of Mercury-Contaminated Environment

Coagulation-Flocculation of Aquaculture Wastewater Using Green Coagulant from Garcinia kola Seeds: Parametric Studies, Kinetic Modelling and Cost Analysis

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