Removal of Hexavalent Chromium in Aqueous Solution by Cellulose Filter Paper Loaded with Nano-Zero-Valent Iron: Performance Investigation and Numerical Modeling

Abstract

Cr(VI) pollution in water bodies is very harmful to human health and the environment. Therefore, it is necessary to remove Cr(VI) from water. In this study, the composite (FP-nZVI) was prepared by loading nano-zero-valent iron (nZVI) onto cellulose filter paper (FP) using a liquid-phase reduction method to improve the dispersibility and oxidation resistance of nZVI. In batch experiments, the effects of iron loading of FP-nZVI, initial concentration of Cr(VI), temperature, and pH on Cr(VI) removal were particularly investigated. The maximum removal rate of 98.6% was achieved at 25 °C, pH = 5, initial concentration of Cr(VI) of 20 mg/L, and FeCl3·6H2O solution concentration of 0.8 mol/L. The removal of Cr(VI) by FP-nZVI conformed to a pseudo-second-order kinetic model and Langmuir isotherm model. The mechanism of Cr(VI) removal was a multi-step removal mechanism, involving adsorption, reduction, and coprecipitation. Column experiments investigated the effect of flow rate (1 mL/min, 3 mL/min, and 5 mL/min) on Cr(VI) removal. We found that increasing flow rate slightly decreased the removal rate of Cr(VI). The transport of Cr(VI) in composite porous media was simulated using HYDRUS-1D, and the results show that the two-site model can well simulate the reactive transport of Cr(VI). This study may provide a useful reference for the remediation of groundwater contaminated with Cr(VI) or other similar heavy metals using FP-nZVI.

Environmental remediation approaches by nanoscale zero valent iron (nZVI) based on its reductivity: a review

“…57 Rice straw-derived hydrothermal carbon and cellulose lter paper have been used as support for nZVI, aiming to improve the dispersibility and oxidation resistance of nZVI during the reduction of Cr(VI). 100,101 Most of the Cr can be recovered from water utilizing the magnetically separating of nZVI material. While the cover of precipitate may reduce the activity of nZVI.…”

“…57 Rice straw-derived hydrothermal carbon and cellulose filter paper have been used as support for nZVI, aiming to improve the dispersibility and oxidation resistance of nZVI during the reduction of Cr( vi ). 100,101…”