This work aimed to
separate emulsified oil from oily sewage by
electrocoagulation (EC). The research was carried out in a continuous
system with aluminum electrodes. The effect of electrodes placement,
including tilt angle of parallel-plate electrodes (APE) and electrodes’
polarity orientation (POE), on EC performance (oil removal and energy
consumption) was studied. A novel reactor, within which the electrodes
with polarity crossly oriented (PC) was compared to that with electrodes’
polarity identically oriented (PI) under different running conditions,
as the APE, applied current density, flow rate, and electrode distance.
To throw light upon the difference of reaction rate between PC and
PI performance, a first-order kinetics equation was established. The
results show that the PC system was more efficient than the PI system,
particularly at lower current densities. At optimum conditions (current
density of 140 A/m2, electrolysis time of 140 min, a flow
rate of 5 L/h, and APE of 76°), 97.6% of emulsified oil was removed
in the PC system with the energy consumption of 0.869 kW·h/m3. By contrast, the removal efficiency in the PI system only
reached 91.4%, which was 6.2% lower than that in the PC system. Besides,
it can be found that the entire EC process can be divided into two
stages: start-up stage and steady state. The higher the current density
and the flow rate, the shorter the start-up time. Evaluation of the
effects of APE indicates that there exists an optimum tilt angle of
electrodes at which the EC performance was better than any other tilt
angles studied.